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The synthesis highlights a one\u2010pot intermolecular ketene esterification reaction to form the crucial tertiary ester and tetrahydropyran. In addition, a novel and concise synthetic pathway towards the 1,3\u2010<jats:italic>syn<\/jats:italic> secondary, tertiary diol fragment is described using a regio\u2010 and stereospecific electrophilic ether transfer reaction.<\/jats:p>","DOI":"10.1002\/chem.201502132","type":"journal-article","created":{"date-parts":[[2015,6,23]],"date-time":"2015-06-23T03:28:38Z","timestamp":1435030118000},"page":"10681-10686","source":"Crossref","is-referenced-by-count":21,"title":["Total Synthesis and Structural Reassignment of Lyngbyaloside C Highlighted by Intermolecular Ketene Esterification"],"prefix":"10.1002","volume":"21","author":[{"given":"Chia\u2010Fu","family":"Chang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric","family":"Stefan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Richard E.","family":"Taylor","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,6,23]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/b208815k"},{"key":"e_1_2_3_3_2","first-page":"45","volume":"26","author":"William P. 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