{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T11:12:52Z","timestamp":1760267572591,"version":"build-2065373602"},"reference-count":56,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2015,8,31]],"date-time":"2015-08-31T00:00:00Z","timestamp":1440979200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]},{"name":"DFG"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,10,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We report the synthesis of [<jats:italic>n<\/jats:italic>]manganoarenophanes (<jats:italic>n<\/jats:italic>=1, 2) featuring boron, silicon, germanium, and tin as <jats:italic>ansa<\/jats:italic>\u2010bridging elements. Their preparation was achieved by salt\u2010elimination reactions of the dilithiated precursor [Mn(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>Li)(\u03b7<jats:sup>6<\/jats:sup>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>Li)]\u22c5pmdta (pmdta=<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>,<jats:italic>N\u2032<\/jats:italic>,<jats:italic>N\u2032<\/jats:italic>,<jats:italic>N\u2032\u2032<\/jats:italic>\u2010pentamethyldiethylenetriamine) with corresponding element dichlorides. Besides characterization by multinuclear NMR spectroscopy and elemental analysis, the identity of two single\u2010atom\u2010bridged derivatives, [Mn(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03b7<jats:sup>6<\/jats:sup>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)Sn<jats:italic>t<\/jats:italic>Bu<jats:sub>2<\/jats:sub>] and [Mn(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03b7<jats:sup>6<\/jats:sup>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)SiPh<jats:sub>2<\/jats:sub>], could also be determined by X\u2010ray structural analysis. We investigated for the first time the reactivity of these <jats:italic>ansa<\/jats:italic>\u2010cyclopentadienyl\u2013benzene manganese compounds. The reaction of the distannyl\u2010bridged complex [Mn(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03b7<jats:sup>6<\/jats:sup>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)Sn<jats:sub>2<\/jats:sub><jats:italic>t<\/jats:italic>Bu<jats:sub>4<\/jats:sub>] with elemental sulfur was shown to proceed through the expected oxidative addition of the Sn\uf8ffSn bond to give a triatomic <jats:italic>ansa<\/jats:italic>\u2010bridge. The investigation of the ring\u2010opening polymerization (ROP) capability of [Mn(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03b7<jats:sup>6<\/jats:sup>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)Sn<jats:italic>t<\/jats:italic>Bu<jats:sub>2<\/jats:sub>] with [Pt(PEt<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>] showed that an unexpected, unselective insertion into the C<jats:sub><jats:italic>ipso<\/jats:italic><\/jats:sub>\uf8ffSn bonds of [Mn(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03b7<jats:sup>6<\/jats:sup>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)Sn<jats:italic>t<\/jats:italic>Bu<jats:sub>2<\/jats:sub>] had occurred.<\/jats:p>","DOI":"10.1002\/chem.201502161","type":"journal-article","created":{"date-parts":[[2015,9,2]],"date-time":"2015-09-02T04:38:04Z","timestamp":1441168684000},"page":"14797-14803","source":"Crossref","is-referenced-by-count":5,"title":["<i>Ansa<\/i>\u2010Complexes of [Mn(\u03b7<sup>5<\/sup>\u2010C<sub>5<\/sub>H<sub>5<\/sub>)(\u03b7<sup>6<\/sup>\u2010C<sub>6<\/sub>H<sub>6<\/sub>)]: Preparation, Characterization, and Reactivity of [<i>n<\/i>]Manganoarenophanes (<i>n<\/i>=1, 2, 3)"],"prefix":"10.1002","volume":"21","author":[{"given":"Holger","family":"Braunschweig","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"Damme","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Klaus","family":"D\u00fcck","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marco","family":"Fu\u00df","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"H\u00f6rl","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thomas","family":"Kramer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ivo","family":"Krummenacher","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thomas","family":"Kupfer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Valerie","family":"Paprocki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christoph","family":"Schneider","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,8,31]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar900234z"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604409"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604409"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b802289e"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460538"},{"key":"e_1_2_6_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460538"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/B417884J"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9080056"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2011.10.005"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/om060928l"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/om060471f"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200400247"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201100919"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja510884h"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0724947"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200500689"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500686"},{"key":"e_1_2_6_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500686"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/om200577b"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2014218"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/om700900e"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199715081"},{"key":"e_1_2_6_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091324"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603130"},{"key":"e_1_2_6_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200603130"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19980615)4:6<1027::AID-CHEM1027>3.0.CO;2-3"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201002614"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja8006879"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/a801935e"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(98)01028-6"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00044a034"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9009813"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/om200214w"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604391"},{"key":"e_1_2_6_29_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604391"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(94)80204-1"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(94)05052-D"},{"key":"e_1_2_6_32_2","doi-asserted-by":"crossref","first-page":"1037","DOI":"10.1515\/znb-1997-0903","volume":"52","author":"Herberhold 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