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Different bonding motifs, such as antiparallel dipolar coupling, hydrogen bonding and metal coordination, were observed. Whereas on Ag(111) only one hexagonally close\u2010packed pattern stabilized by hydrogen bonding is observed, on Au(111) two different partially porous phases are present at submonolayer coverage, stabilized by dipolar coupling, hydrogen bonding and metal coordination. In contrast to the self\u2010assembly on Ag(111) and Au(111), for which large islands are formed, on Cu(111), only small patches of hexagonally close\u2010packed networks stabilized by metal coordination and areas of disordered molecules are found. The significant variety in the molecular self\u2010assembly of the cyano\u2010functionalized triarylamine derivatives on these coinage metal surfaces is explained by differences in molecular mobility and the subtle interplay between intermolecular and molecule\u2013substrate interactions.<\/jats:p>","DOI":"10.1002\/chem.201503205","type":"journal-article","created":{"date-parts":[[2015,12,4]],"date-time":"2015-12-04T09:56:11Z","timestamp":1449222971000},"page":"581-589","source":"Crossref","is-referenced-by-count":40,"title":["Cyano\u2010Functionalized Triarylamines on Coinage Metal Surfaces: Interplay of Intermolecular and Molecule\u2013Substrate Interactions"],"prefix":"10.1002","volume":"22","author":[{"given":"Kathrin","family":"M\u00fcller","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juan 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