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The azides were isolated on the 0.3 to 1\u2005g scale and characterized by IR and NMR spectroscopies, microanalytical and thermal methods and their molecular structures determined by single\u2010crystal XRD. All complexes have a distorted octahedral Sn[N]<jats:sub>6<\/jats:sub> coordination geometry and possess greater thermal stability than their Si and Ge homologues. The nitrogen content of the adducts of up to 44\u2009% exceed any Sn<jats:sup>IV<\/jats:sup> compound known hitherto.<\/jats:p>","DOI":"10.1002\/chem.201503478","type":"journal-article","created":{"date-parts":[[2015,11,13]],"date-time":"2015-11-13T05:39:03Z","timestamp":1447393143000},"page":"18690-18698","source":"Crossref","is-referenced-by-count":9,"title":["Taming Tin(IV) Polyazides"],"prefix":"10.1002","volume":"21","author":[{"given":"Rory","family":"Campbell","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martin F.","family":"Davis","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mathew","family":"Fazakerley","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter","family":"Portius","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,11,13]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.09.019"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201300162"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200702758"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201103101"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp052726t"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603960"},{"key":"e_1_2_6_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200603960"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001826"},{"key":"e_1_2_6_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201001826"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.189102402192"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404561"},{"key":"e_1_2_6_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404561"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.5012\/bkcs.2010.31.04.781"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0273187"},{"key":"e_1_2_6_13_2","unstructured":"\u00a0"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20001201)39:23<4333::AID-ANIE4333>3.0.CO;2-S"},{"key":"e_1_2_6_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20001201)112:23<4524::AID-ANGE4524>3.0.CO;2-S"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic400866c"},{"key":"e_1_2_6_15_3","doi-asserted-by":"publisher","DOI":"10.1021\/ic400866c"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50013a022"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50016a025"},{"key":"e_1_2_6_18_2","first-page":"500","volume":"9","author":"Wiberg E.","year":"1954","journal-title":"Z. 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