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NMR experiments clearly suggest a stepwise formation of <jats:bold>1<\/jats:bold> through <jats:bold>4<\/jats:bold> by subsequent condensation steps with the concomitant release of Me<jats:sub>3<\/jats:sub>SiCl. Furthermore, addition of hydrazines to the keto\u2010functionalized clusters leads to the formation of hydrazone derivatives, [(Sn<jats:sub>2<\/jats:sub>(\u03bc\u2010R<jats:sup>3<\/jats:sup>)(\u03bc\u2010Se)Cl<jats:sub>4<\/jats:sub>] (<jats:bold>5<\/jats:bold>, R<jats:sup>3<\/jats:sup>=[CMe<jats:sub>2<\/jats:sub>CH<jats:sub>2<\/jats:sub>CMe(NH)]<jats:sub>2<\/jats:sub>), [(SnR<jats:sup>2<\/jats:sup>)<jats:sub>3<\/jats:sub>Se<jats:sub>4<\/jats:sub>Cl] (<jats:bold>6<\/jats:bold>, R<jats:sup>2<\/jats:sup>=CMe<jats:sub>2<\/jats:sub>CH<jats:sub>2<\/jats:sub>C(NNH<jats:sub>2<\/jats:sub>)Me), [(SnR<jats:sup>4<\/jats:sup>)<jats:sub>3<\/jats:sub>Se<jats:sub>4<\/jats:sub>][SnCl<jats:sub>3<\/jats:sub>] (<jats:bold>7<\/jats:bold>, R<jats:sup>4<\/jats:sup>=CMe<jats:sub>2<\/jats:sub>CH<jats:sub>2<\/jats:sub>C(NNHPh)Me), [(SnR<jats:sup>2<\/jats:sup>)<jats:sub>4<\/jats:sub>Se<jats:sub>6<\/jats:sub>] (<jats:bold>8<\/jats:bold>), and [(SnR<jats:sup>4<\/jats:sup>)<jats:sub>4<\/jats:sub>Se<jats:sub>6<\/jats:sub>] (<jats:bold>9<\/jats:bold>). Upon treatment of <jats:bold>4<\/jats:bold> with [Cu(PPh<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>Cl] and excess (SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>Se, the cluster fragments to form [(R<jats:sup>1<\/jats:sup>Sn)<jats:sub>2<\/jats:sub>Se<jats:sub>2<\/jats:sub>(CuPPh<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>Se<jats:sub>2<\/jats:sub>] (<jats:bold>10<\/jats:bold>), the first discrete Sn\/Se\/Cu cluster compound reported in the literature. The derivatization reactions indicate fundamental differences between organotin sulfide and organotin selenide chemistry.<\/jats:p>","DOI":"10.1002\/chem.201503562","type":"journal-article","created":{"date-parts":[[2016,1,25]],"date-time":"2016-01-25T11:53:30Z","timestamp":1453722810000},"page":"3094-3104","source":"Crossref","is-referenced-by-count":28,"title":["Formation and Reactivity of Organo\u2010Functionalized Tin Selenide Clusters"],"prefix":"10.1002","volume":"22","author":[{"given":"Niklas","family":"Rinn","sequence":"first","affiliation":[{"name":"Fachbereich Chemie and Wissenschaftliches Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 35043 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jens P.","family":"Eu\u00dfner","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie and Wissenschaftliches Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t 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