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This paper presents a rationalization of all the experimental findings in a unifying picture to cast light on the basic chemical properties of Ng* under conditions of great relevance both from a fundamental and from an applied point of view. The importance of this investigation is that it isolates the selective role of the intermolecular halogen and hydrogen bonds, to assess their anisotropic effects on the stereodynamics of the promoted ionization reactions, and to model energy transfer and reactivity in systems of applied interest, such as planetary atmospheres, plasmas, lasers, and flames.<\/jats:p>","DOI":"10.1002\/chem.201503692","type":"journal-article","created":{"date-parts":[[2015,12,3]],"date-time":"2015-12-03T08:31:09Z","timestamp":1449131469000},"page":"764-771","source":"Crossref","is-referenced-by-count":44,"title":["Stereodynamics in the Collisional Autoionization of Water, Ammonia, and Hydrogen Sulfide with Metastable Rare Gas Atoms: Competition Between Intermolecular Halogen and Hydrogen Bonds"],"prefix":"10.1002","volume":"22","author":[{"given":"Stefano","family":"Falcinelli","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alessio","family":"Bartocci","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Simonetta","family":"Cavalli","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fernando","family":"Pirani","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Franco","family":"Vecchiocattivi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,12,3]]},"reference":[{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406103"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1103\/RevModPhys.65.337"},{"key":"e_1_2_7_3_2","first-page":"359","volume-title":"Ion Clusters","author":"Brunetti B. 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