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The formation of this compound was investigated by spectroscopic and theoretical methods, revealing an unusual ring expansion reaction. The title compound was fully characterized by experimental and computational methods.<\/jats:p>","DOI":"10.1002\/chem.201503808","type":"journal-article","created":{"date-parts":[[2015,10,14]],"date-time":"2015-10-14T05:19:39Z","timestamp":1444799979000},"page":"18543-18546","source":"Crossref","is-referenced-by-count":11,"title":["A Tricyclic Hexaphosphane"],"prefix":"10.1002","volume":"21","author":[{"given":"Jonas","family":"Bresien","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Axel","family":"Schulz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Villinger","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,11,5]]},"reference":[{"key":"e_1_2_4_1_2","first-page":"236","volume-title":"Allgemeine Deutsche Biographie, Dritter Band","author":"Oppenheim A.","year":"1876"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2010.12.016"},{"key":"e_1_2_4_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00020a010"},{"key":"e_1_2_4_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400547x"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.458306"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19921251211"},{"key":"e_1_2_4_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00050a039"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00039a058"},{"key":"e_1_2_4_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00094a053"},{"key":"e_1_2_4_11_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.468552"},{"key":"e_1_2_4_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.theochem.2004.02.014"},{"key":"e_1_2_4_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp21959f"},{"key":"e_1_2_4_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198109672"},{"key":"e_1_2_4_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19810931125"},{"key":"e_1_2_4_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198604711"},{"key":"e_1_2_4_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19860980524"},{"key":"e_1_2_4_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198906001"},{"key":"e_1_2_4_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19891010519"},{"key":"e_1_2_4_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19911240112"},{"key":"e_1_2_4_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200804903"},{"key":"e_1_2_4_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200804903"},{"key":"e_1_2_4_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503074"},{"key":"e_1_2_4_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201503074"},{"key":"e_1_2_4_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19693690111"},{"key":"e_1_2_4_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201403631"},{"key":"e_1_2_4_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198510561"},{"key":"e_1_2_4_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19850971211"},{"key":"e_1_2_4_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703055"},{"key":"e_1_2_4_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703055"},{"key":"e_1_2_4_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201405879"},{"key":"e_1_2_4_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201405879"},{"key":"e_1_2_4_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201403295"},{"key":"e_1_2_4_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201403295"},{"key":"e_1_2_4_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201500892"},{"key":"e_1_2_4_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201500892"},{"key":"e_1_2_4_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja039549z"},{"key":"e_1_2_4_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/b710853b"},{"key":"e_1_2_4_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500395"},{"key":"e_1_2_4_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19855280902"},{"key":"e_1_2_4_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic8016003"},{"key":"e_1_2_4_32_2","unstructured":"CCDC\u20051417832\u2005(6) contain the supplementary crystallographic data for this paper. 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