{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T21:59:38Z","timestamp":1790027978903,"version":"4.0.1"},"reference-count":68,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2015,12,18]],"date-time":"2015-12-18T00:00:00Z","timestamp":1450396800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["WE 5627\/1-1"],"award-info":[{"award-number":["WE 5627\/1-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2016,1,26]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Anionic two\u2010coordinate complexes of first\u2010row transition\u2010metal(I) centres are rare molecules that are expected to reveal new magnetic properties and reactivity. Recently, we demonstrated that a N(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub><jats:sup>\u2212<\/jats:sup> ligand set, which is unable to prevent dimerisation or extraneous ligand coordination at the +2 oxidation state of iron, was nonetheless able to stabilise anionic two\u2010coordinate Fe<jats:sup>I<\/jats:sup> complexes even in the presence of a Lewis base. We now report analogous Cr<jats:sup>I<\/jats:sup> and Co<jats:sup>I<\/jats:sup> complexes with exclusively this amido ligand and the isolation of a [Mn<jats:sup>I<\/jats:sup>{N(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub><jats:sup>2\u2212<\/jats:sup> dimer that features a Mn\u2212Mn bond. Additionally, by increasing the steric hindrance of the ligand set, the two\u2010coordinate complex [Mn<jats:sup>I<\/jats:sup>{N(Dipp)(SiMe<jats:sub>3<\/jats:sub>)}<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup> was isolated (Dipp=2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>). Characterisation of these compounds by using X\u2010ray crystallography, NMR spectroscopy, and magnetic susceptibility measurements is provided along with ligand\u2010field analysis based on CASSCF\/NEVPT2 ab initio calculations.<\/jats:p>","DOI":"10.1002\/chem.201503980","type":"journal-article","created":{"date-parts":[[2015,12,18]],"date-time":"2015-12-18T20:17:08Z","timestamp":1450469828000},"page":"1668-1674","source":"Crossref","is-referenced-by-count":79,"title":["Homoleptic Two\u2010Coordinate Silylamido Complexes of Chromium(I), Manganese(I), and Cobalt(I)"],"prefix":"10.1002","volume":"22","author":[{"given":"C. Gunnar","family":"Werncke","sequence":"first","affiliation":[{"name":"CNRS LCC (Laboratoire de Chimie de Coordination)  205 route de Narbonne, 31077 Toulouse (France) and Universit\u00e9 de Toulouse, UPS, INPT 31077 Toulouse France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elizaveta","family":"Suturina","sequence":"additional","affiliation":[{"name":"Max-Planck-Institute for Chemical Energy Conversion  Stiftstrasse 34\u201336 M\u00fchlheim an der Ruhr 45470 Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philip C.","family":"Bunting","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California, Berkeley  Berkeley California 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laure","family":"Vendier","sequence":"additional","affiliation":[{"name":"CNRS LCC (Laboratoire de Chimie de Coordination)  205 route de Narbonne, 31077 Toulouse (France) and Universit\u00e9 de Toulouse, UPS, INPT 31077 Toulouse France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeffrey R.","family":"Long","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California, Berkeley  Berkeley California 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mihail","family":"Atanasov","sequence":"additional","affiliation":[{"name":"Max-Planck-Institute for Chemical Energy Conversion  Stiftstrasse 34\u201336 M\u00fchlheim an der Ruhr 45470 Germany"},{"name":"Institute of General and Inorganic Chemistry Bulgarian Academy of Sciences  1113 Sofia Bulgaria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frank","family":"Neese","sequence":"additional","affiliation":[{"name":"Max-Planck-Institute for Chemical Energy Conversion  Stiftstrasse 34\u201336 M\u00fchlheim an der Ruhr 45470 Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sylviane","family":"Sabo\u2010Etienne","sequence":"additional","affiliation":[{"name":"CNRS LCC (Laboratoire de Chimie de Coordination)  205 route de Narbonne, 31077 Toulouse (France) and Universit\u00e9 de Toulouse, UPS, INPT 31077 Toulouse France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S\u00e9bastien","family":"Bontemps","sequence":"additional","affiliation":[{"name":"CNRS LCC (Laboratoire de Chimie de Coordination)  205 route de Narbonne, 31077 Toulouse (France) and Universit\u00e9 de Toulouse, UPS, INPT 31077 Toulouse France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,12,18]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0DT01247E"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr2004647"},{"key":"e_1_2_6_4_1","unstructured":"For anionic two-coordinate metal(I) complexes see:"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1630"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic402013n"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja408151h"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC06615D"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic501534f"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC05166E"},{"key":"e_1_2_6_11_1","unstructured":"For neutral and cationic two-coordinate 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