{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,22]],"date-time":"2025-12-22T10:27:45Z","timestamp":1766399265787,"version":"build-2065373602"},"reference-count":59,"publisher":"Wiley","issue":"52","license":[{"start":{"date-parts":[[2015,11,23]],"date-time":"2015-11-23T00:00:00Z","timestamp":1448236800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","award":["DR-17\/2"],"award-info":[{"award-number":["DR-17\/2"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]},{"name":"New Sz\u00e9chenyi Plan","award":["TAMOP-4.2.2\/B-10\/1-2010-0009"],"award-info":[{"award-number":["TAMOP-4.2.2\/B-10\/1-2010-0009"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,12,21]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Reaction of the arylchlorosilylene\u2010NHC adduct ArSi(NHC)Cl [Ar=2,6\u2010Trip<jats:sub>2<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>; NHC=(MeC)<jats:sub>2<\/jats:sub>(NMe)<jats:sub>2<\/jats:sub>C:] <jats:bold>1<\/jats:bold> with one molar equiv of lithium diphenylphosphanide affords the first stable NHC\u2010stabilized acyclic phosphinosilylene adduct <jats:bold>2<\/jats:bold> (ArSi(NHC)PPh<jats:sub>2<\/jats:sub>), which could be structurally characterized. Compound <jats:bold>2<\/jats:bold>, when reacted with one molar equiv selenium and sulfur, affords the silanechalcogenones <jats:bold>4\u2009a<\/jats:bold> and <jats:bold>4\u2009b<\/jats:bold> (ArSi(NHC)(\uf8feE)PPh<jats:sub>2<\/jats:sub>, <jats:bold>4\u2009a<\/jats:bold>: E=Se, <jats:bold>4\u2009b<\/jats:bold>: E=S), respectively. Conversion of <jats:bold>2<\/jats:bold> with an excess of Se and S, through additional insertion of one chalcogen atom into the Si\uf8ffP bond, leads to <jats:bold>3\u2009a<\/jats:bold> and <jats:bold>3\u2009b<\/jats:bold> (ArSi(NHC)(\uf8feE)\u2010E\u2010P(\uf8feE)Ph<jats:sub>2<\/jats:sub>, <jats:bold>3\u2009a<\/jats:bold>: E=Se, <jats:bold>3\u2009b<\/jats:bold>: E=S), respectively. Additionally, the exposure of <jats:bold>2<\/jats:bold> to N<jats:sub>2<\/jats:sub>O or CO<jats:sub>2<\/jats:sub> yielded the isolable NHC\u2010stabilized silanone <jats:bold>4\u2009c<\/jats:bold>, Ar(NHC)(Ph<jats:sub>2<\/jats:sub>P)Si\uf8feO.<\/jats:p>","DOI":"10.1002\/chem.201504113","type":"journal-article","created":{"date-parts":[[2015,11,23]],"date-time":"2015-11-23T07:48:33Z","timestamp":1448264913000},"page":"18930-18933","source":"Crossref","is-referenced-by-count":34,"title":["From an Isolable Acyclic Phosphinosilylene Adduct to Donor\u2010Stabilized Si\uf8feE Compounds (E=O, S, Se)"],"prefix":"10.1002","volume":"21","author":[{"given":"Kerstin","family":"Hansen","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tibor","family":"Szilv\u00e1si","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Burgert","family":"Blom","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Elisabeth","family":"Irran","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Matthias","family":"Driess","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,11,23]]},"reference":[{"key":"e_1_2_3_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00085a088"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39950001931"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1351\/pac199668040785"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar950192g"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200500005"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja062928i"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/om060544v"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1160768"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600647"},{"key":"e_1_2_3_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200600647"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/b905905a"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/om8006147"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja106458p"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2009.10.034"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202175"},{"key":"e_1_2_3_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201202175"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201200632"},{"key":"e_1_2_3_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201200632"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja980008x"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja035374h"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt11592h"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201202195"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203257"},{"key":"e_1_2_3_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201203257"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja301180v"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja410528y"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja403802a"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901766"},{"key":"e_1_2_3_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200901766"},{"key":"e_1_2_3_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102659"},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301363"},{"key":"e_1_2_3_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201301363"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja301091v"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja301042u"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201208554"},{"key":"e_1_2_3_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201208554"},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/b903098k"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200903019"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/om3008184"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9031049"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1993-25902"},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1977-0507"},{"key":"e_1_2_3_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00040a007"},{"key":"e_1_2_3_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja065774f"},{"key":"e_1_2_3_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200700285"},{"key":"e_1_2_3_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902467"},{"key":"e_1_2_3_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201002611"},{"key":"e_1_2_3_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201202936"},{"key":"e_1_2_3_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201300255"},{"key":"e_1_2_3_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201500108"},{"key":"e_1_2_3_45_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)85872-6"},{"key":"e_1_2_3_46_2","doi-asserted-by":"publisher","DOI":"10.1139\/v80-346"},{"key":"e_1_2_3_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209766"},{"key":"e_1_2_3_47_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209766"},{"key":"e_1_2_3_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201501844"},{"key":"e_1_2_3_48_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201501844"},{"key":"e_1_2_3_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308433"},{"key":"e_1_2_3_49_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308433"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201504113","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201504113","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.201504113","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201504113","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T16:30:30Z","timestamp":1760286630000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201504113"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,11,23]]},"references-count":59,"journal-issue":{"issue":"52","published-print":{"date-parts":[[2015,12,21]]}},"alternative-id":["10.1002\/chem.201504113"],"URL":"https:\/\/doi.org\/10.1002\/chem.201504113","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2015,11,23]]}}}