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All [PF<jats:sub>6\u2212<jats:italic>n<\/jats:italic><\/jats:sub>(CN)<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>]<jats:sup>\u2212<\/jats:sup> (<jats:italic>n<\/jats:italic>=1\u20134) salts could be isolated on a preparative scale. It was also possible to detect the [PF(CN)<jats:sub>5<\/jats:sub>]<jats:sup>\u2212<\/jats:sup> but not the [P(CN)<jats:sub>6<\/jats:sub>]<jats:sup>\u2212<\/jats:sup> anion. The best results with respect to purity, yield, and low cost were obtained when the F<jats:sup>\u2212<\/jats:sup>\/CN<jats:sup>\u2212<\/jats:sup> substitution reactions were carried out in ionic liquids.<\/jats:p>","DOI":"10.1002\/chem.201504523","type":"journal-article","created":{"date-parts":[[2016,2,5]],"date-time":"2016-02-05T12:00:54Z","timestamp":1454673654000},"page":"4175-4188","source":"Crossref","is-referenced-by-count":16,"title":["Lewis Acid Catalyzed Synthesis of Cyanidophosphates"],"prefix":"10.1002","volume":"22","author":[{"given":"Kevin","family":"Bl\u00e4sing","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Strasse 3a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan","family":"Ellinger","sequence":"additional","affiliation":[{"name":"Lonzastrasse 3930 Visp Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00f6rg","family":"Harloff","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Strasse 3a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9060-7065","authenticated-orcid":false,"given":"Axel","family":"Schulz","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Strasse 3a 18059 Rostock Germany"},{"name":"Abteilung Materialdesign Leibniz-Institut f\u00fcr Katalyse e.V. an der Universit\u00e4t Rostock  Albert-Einstein-Strasse 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katharina","family":"Sievert","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Strasse 3a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christoph","family":"T\u00e4schler","sequence":"additional","affiliation":[{"name":"Lonzastrasse 3930 Visp Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Villinger","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Strasse 3a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cornelia","family":"Zur\u2005T\u00e4schler","sequence":"additional","affiliation":[{"name":"Lonzastrasse 3930 Visp Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,2,5]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/dt9820001199"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-1902(80)80103-5"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951070504"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)81526-0"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/dt9830001159"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/dt9800001036"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C39790000889"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19670791409"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19300630237"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196703631"},{"key":"e_1_2_6_10_2","first-page":"316","volume":"79","year":"1967","journal-title":"Angew. 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