{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T10:17:05Z","timestamp":1787653025482,"version":"build-2736575974"},"reference-count":122,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2016,3,2]],"date-time":"2016-03-02T00:00:00Z","timestamp":1456876800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Ministry of Education of the Czech Republic"},{"DOI":"10.13039\/501100001824","name":"Czech Science Foundation","doi-asserted-by":"crossref","award":["15-07091S"],"award-info":[{"award-number":["15-07091S"]}],"id":[{"id":"10.13039\/501100001824","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Research Foundation-Flanders (FWO)","award":["12T6615N"],"award-info":[{"award-number":["12T6615N"]}]},{"name":"Research Foundation-Flanders (FWO)","award":["12F4416N"],"award-info":[{"award-number":["12F4416N"]}]},{"name":"VUB"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2016,4,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Our attempts to synthesise N\u2192M intramolecularly coordinated diorganometallic hydrides L<jats:sub>2<\/jats:sub>MH<jats:sub>2<\/jats:sub> [M=Si (<jats:bold>4<\/jats:bold>), Ge (<jats:bold>5<\/jats:bold>), Sn (<jats:bold>6<\/jats:bold>)] containing the CH=N imine group (in which L is C,N\u2010chelating ligand {2\u2010[(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)N=CH]C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>}<jats:sup>\u2212<\/jats:sup>) yielded 1,1\u2032\u2010bis(2,6\u2010diisopropylphenyl)\u20102,2\u2032\u2010spriobi[benzo[<jats:italic>c<\/jats:italic>][1,2]azasilole] (<jats:bold>7<\/jats:bold>), 1,1\u2032\u2010bis(2,6\u2010diisopropylphenyl)\u20102,2\u2032\u2010spriobi[benzo[<jats:italic>c<\/jats:italic>][1,2]azagermole] (<jats:bold>8<\/jats:bold>) and <jats:italic>C<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2010chelated homoleptic stannylene L<jats:sub>2<\/jats:sub>Sn (<jats:bold>10<\/jats:bold>), respectively. Compounds <jats:bold>7<\/jats:bold> and <jats:bold>8<\/jats:bold> are an outcome of a spontaneous double hydrometallation of the two CH=N imine moieties induced by N\u2192M intramolecular coordination (M=Si, Ge) in the absence of any catalyst. In contrast, the diorganotin hydride L<jats:sub>2<\/jats:sub>SnH<jats:sub>2<\/jats:sub> (<jats:bold>6<\/jats:bold>) is redox\u2010unstable and the reduction of the tin centre with the elimination of H<jats:sub>2<\/jats:sub> provided the <jats:italic>C<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2010chelated homoleptic stannylene L<jats:sub>2<\/jats:sub>Sn (<jats:bold>10<\/jats:bold>). Compounds <jats:bold>7<\/jats:bold> and <jats:bold>8<\/jats:bold> were characterised by NMR spectroscopy and X\u2010ray diffraction analysis. Because the proposed N\u2192M intramolecularly coordinated diorganometallic hydrides L<jats:sub>2<\/jats:sub>MH<jats:sub>2<\/jats:sub> [M=Si (<jats:bold>4<\/jats:bold>), Ge (<jats:bold>5<\/jats:bold>), Sn (<jats:bold>6<\/jats:bold>)] revealed two different types of reduction reactions, DFT calculations were performed to gain an insight into the structures and bonding of the non\u2010isolable diorganometallic hydrides as well as the products of their subsequent reactions. Furthermore, the thermodynamic profiles of the different reaction pathways with respect to the central metal atom were also investigated.<\/jats:p>","DOI":"10.1002\/chem.201504947","type":"journal-article","created":{"date-parts":[[2016,3,2]],"date-time":"2016-03-02T12:14:06Z","timestamp":1456920846000},"page":"5620-5628","source":"Crossref","is-referenced-by-count":17,"title":["Spontaneous Double Hydrometallation Induced by N\u2192M Coordination in Organometallic Hydrides of Group 14 Elements"],"prefix":"10.1002","volume":"22","author":[{"given":"Miroslav","family":"Nov\u00e1k","sequence":"first","affiliation":[{"name":"Department of General and Inorganic Chemistry Faculty of Chemical Technology University of Pardubice  Studentsk\u00e1\u200595 53210 Pardubice Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Libor","family":"Dost\u00e1l","sequence":"additional","affiliation":[{"name":"Department of General and Inorganic Chemistry Faculty of Chemical Technology University of Pardubice  Studentsk\u00e1\u200595 53210 Pardubice Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan","family":"Turek","sequence":"additional","affiliation":[{"name":"Eenheid Algemene Chemie (ALGC) Member of the QCMM VUB-UGent Alliance Research Group Vrije Universiteit Brussel  Pleinlaan\u20052 1050 Brussels Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mercedes","family":"Alonso","sequence":"additional","affiliation":[{"name":"Eenheid Algemene Chemie (ALGC) Member of the QCMM VUB-UGent Alliance Research Group Vrije Universiteit Brussel  Pleinlaan\u20052 1050 Brussels Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frank","family":"De\u2005Proft","sequence":"additional","affiliation":[{"name":"Eenheid Algemene Chemie (ALGC) Member of the QCMM VUB-UGent Alliance Research Group Vrije Universiteit Brussel  Pleinlaan\u20052 1050 Brussels Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ale\u0161","family":"R\u016f\u017ei\u010dka","sequence":"additional","affiliation":[{"name":"Department of General and Inorganic Chemistry Faculty of Chemical Technology University of Pardubice  Studentsk\u00e1\u200595 53210 Pardubice Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roman","family":"Jambor","sequence":"additional","affiliation":[{"name":"Department of General and Inorganic Chemistry Faculty of Chemical Technology University of Pardubice  Studentsk\u00e1\u200595 53210 Pardubice Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,3,2]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/0470025107.ch25"},{"key":"e_1_2_6_3_2","first-page":"8","volume-title":"Comprehensive Handbook on Hydrosilylation","author":"Marciniec B.","year":"1992"},{"key":"e_1_2_6_4_2","doi-asserted-by":"crossref","first-page":"763","DOI":"10.1016\/B978-0-08-052349-1.00245-6","volume-title":"Comprehensive Organic Synthesis, Vol.\u20058","author":"Hiyama T.","year":"1991"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00032a028"},{"key":"e_1_2_6_6_2","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1016\/B978-0-08-092493-9.50009-8","volume-title":"Asymmetric Synthesis, Vol.\u20055","author":"Ojima I.","year":"1985"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ba-1979-0173.ch006"},{"key":"e_1_2_6_8_1","unstructured":"\u00a0"},{"key":"e_1_2_6_9_2","first-page":"10","volume-title":"Comprehensive Organometallic Chemistry\u2005I, Vol.\u20052","author":"Wilkinson G.","year":"1982"},{"key":"e_1_2_6_10_2","first-page":"5","volume-title":"Comprehensive Organometallic Chemistry\u2005II, Vol.\u20052","author":"Wilkinson G.","year":"1995"},{"key":"e_1_2_6_11_1","unstructured":"\u00a0"},{"key":"e_1_2_6_12_2","first-page":"159","volume-title":"Science of Synthesis, Vol.\u20054","author":"Pietruszka J.","year":"2001"},{"key":"e_1_2_6_13_2","first-page":"9","volume-title":"Science of Synthesis, Vol.\u20055","author":"Oshima K.","year":"2002"},{"key":"e_1_2_6_14_2","first-page":"205","volume-title":"Science of Synthesis, Vol.\u20055","author":"Clark A. 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