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The results suggest that substituted amines and monocarboxylic type organic or inorganic acids via dual activation mechanisms promote both activation and decomposition reactions, implying that the judicious selection of a dual catalyst is crucial to the efficient C\u2212S bond formation via CO<jats:sub>2<\/jats:sub> activation. Considering that our results also suggest a new mechanism for the formation of carbonyl sulfide from CO<jats:sub>2<\/jats:sub> and H<jats:sub>2<\/jats:sub>S, these new insights may help in better understanding the coupling between the carbon and sulfur cycles in the atmospheres of Earth and Venus.<\/jats:p>","DOI":"10.1002\/chem.201504953","type":"journal-article","created":{"date-parts":[[2016,1,19]],"date-time":"2016-01-19T08:19:23Z","timestamp":1453191563000},"page":"4359-4363","source":"Crossref","is-referenced-by-count":7,"title":["Hydrogen Sulfide Induced Carbon Dioxide Activation by Metal\u2010Free Dual Catalysis"],"prefix":"10.1002","volume":"22","author":[{"given":"Manoj","family":"Kumar","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Nebraska-Lincoln  Lincoln NE 68588 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Joseph S.","family":"Francisco","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Nebraska-Lincoln  Lincoln NE 68588 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,2,16]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"crossref","unstructured":"R.\u2005F. 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