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The reaction of <jats:bold>1<\/jats:bold> with 1,4\u2010benzodinitrile gave [1,4\u2010{{W(CO)<jats:sub>5<\/jats:sub>}<jats:sub>2<\/jats:sub>P\u2010N=C(Cp*)}<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>)] (<jats:bold>3<\/jats:bold>), the first example of a cumulene\u2010like aminophosphinidene complex. The reaction of <jats:bold>1<\/jats:bold> with aniline gave the aminophosphinidene complex [(Ph)N(H)P{W(CO)<jats:sub>5<\/jats:sub>}<jats:sub>2<\/jats:sub>] (<jats:bold>4<\/jats:bold>). To compare the reactivity of benzonitrile and aniline with <jats:bold>1<\/jats:bold>, the phosphinidene complex <jats:bold>1<\/jats:bold> was reacted with three different isomers of aminobenzonitrile (2\u2010, 3\u2010, and 4\u2010aminobenzonitrile). These reactions gave an insight into the reaction pathway of <jats:bold>1<\/jats:bold> with benzonitrile derivatives. Compounds <jats:bold>5<\/jats:bold>, <jats:bold>6\u2009a<\/jats:bold>, <jats:bold>6\u2009b<\/jats:bold>, and <jats:bold>7<\/jats:bold>, which are derivatives of 1,2\u2010dihydro\u20101,3,2\u2010diazaphosphinine or benzo\u20102<jats:italic>H<\/jats:italic>\u20101,2\u2010azaphospholes, were, as well as all other products, characterized by mass spectrometry, NMR and IR spectroscopy, and X\u2010ray structure analysis.<\/jats:p>","DOI":"10.1002\/chem.201504954","type":"journal-article","created":{"date-parts":[[2016,2,18]],"date-time":"2016-02-18T08:03:44Z","timestamp":1455782624000},"page":"5484-5488","source":"Crossref","is-referenced-by-count":10,"title":["Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles"],"prefix":"10.1002","volume":"22","author":[{"given":"Michael","family":"Seidl","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie der Universit\u00e4t Regensburg  93040 Regensburg 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Fox T. Keith M.\u2005A. Al-Laham C.\u2005Y. Peng A. Nanayakkara M. Challacombe P.\u2005M.\u2005W. Gill B. Johnson W. Chen M.\u2005W. Wong C. Gonzalez J.\u2005A. Pople Gaussian03 revision B.05. Gaussian Inc. Wallingford CT 2004."},{"key":"e_1_2_2_74_1","unstructured":"The relative amounts of the reaction products obtained by the integration of the31P\u2005NMR spectra are given in parenthesis."},{"key":"e_1_2_2_75_1","unstructured":"Our previous computations on bridged pentelidene complexes with isonitriles (ref.\u2005[9]) indicate that the gas phase energies and PCM values in toluene solution are close (the maximal difference does not exceed 12\u2005kJ\u2009mol\u22121). 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