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Depending on the size of the substituent and the mode of generation, the intermediates undergo further reactions. Herein, we report on the formation of a variety of organotin hydrides with tin in the oxidation states Sn<jats:sup>II<\/jats:sup>, Sn<jats:sup>I<\/jats:sup>\u2013Sn<jats:sup>III<\/jats:sup> and Sn<jats:sup>III<\/jats:sup>\u2013Sn<jats:sup>III<\/jats:sup>, all accessed by the controlled removal of hydrogen from the tetravalent Ar\u2032Sn<jats:sup>IV<\/jats:sup> trihydride (Ar\u2032=2,6\u2010dimesitylphenyl, mesityl=2,4,6\u2010trimethylphenyl).<\/jats:p>","DOI":"10.1002\/chem.201505081","type":"journal-article","created":{"date-parts":[[2016,4,26]],"date-time":"2016-04-26T22:08:21Z","timestamp":1461708501000},"page":"7554-7566","source":"Crossref","is-referenced-by-count":41,"title":["Access to Base Adducts of Low\u2010Valent Organotin\u2010Hydride Compounds by Controlled, Stepwise Hydrogen Abstraction from a Tetravalent Organotin Trihydride"],"prefix":"10.1002","volume":"22","author":[{"given":"Christian P.","family":"Sindlinger","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Eberhard Karls Universit\u00e4t T\u00fcbingen  Auf der Morgenstelle 18 72076 T\u00fcbingen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wiebke","family":"Grahneis","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Eberhard Karls Universit\u00e4t T\u00fcbingen  Auf der Morgenstelle 18 72076 T\u00fcbingen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Frederik S. 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