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In\u2010line quenching with carbon disulfide revealed that the homogeneous strategy was most efficient for the preparation of a small library of NHCs. The generation of free nucleophilic carbenes was next telescoped with two benchmark NHC\u2010catalyzed reactions; namely, the transesterification of vinyl acetate with benzyl alcohol and the amidation of\n                    <jats:italic>N<\/jats:italic>\n                    \u2010Boc\u2010glycine methyl ester with ethanolamine. Both organocatalytic transformations proceeded with total conversion and excellent yields were achieved after extraction, showcasing the first examples of continuous\u2010flow organocatalysis with NHCs.\n                  <\/jats:p>","DOI":"10.1002\/chem.201505135","type":"journal-article","created":{"date-parts":[[2016,2,16]],"date-time":"2016-02-16T05:00:48Z","timestamp":1455598848000},"page":"4508-4514","source":"Crossref","is-referenced-by-count":29,"title":["Continuous\u2010Flow N\u2010Heterocyclic Carbene Generation and Organocatalysis"],"prefix":"10.1002","volume":"22","author":[{"given":"Lorenzo","family":"Di\u2005Marco","sequence":"first","affiliation":[{"name":"Center for Integrated Technology and Organic Synthesis Department of Chemistry University of Li\u00e8ge  4000 Li\u00e8ge Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Morgan","family":"Hans","sequence":"additional","affiliation":[{"name":"Center for Integrated Technology and Organic Synthesis 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