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Crystallization of this compound is induced by a biomineralization\u2010inspired method with polymer\u2010stabilized amorphous precursors. The crystals grow radially on polymer matrices, leading to the formation of zinc hydroxide carbonate\/polymer thin\u2010film hybrids that fully cover the substrate. These hybrids are converted into ZnO and retain their thin\u2010film morphologies. The resultant ZnO thin films exhibit a preferential crystallographic orientation that is attributed to the alignment of zinc hydroxide carbonate crystals before conversion. In addition, a photocatalytic function of the ZnO thin films has been demonstrated by analyzing the oxidation reaction of 2\u2010propanol. The biomineralization\u2010inspired approach reported herein is a promising way to develop ZnO materials with controlled morphologies and structures for photocatalytic applications.<\/jats:p>","DOI":"10.1002\/chem.201600141","type":"journal-article","created":{"date-parts":[[2016,4,10]],"date-time":"2016-04-10T13:55:19Z","timestamp":1460296519000},"page":"7094-7101","source":"Crossref","is-referenced-by-count":17,"title":["Biomineralization\u2010Inspired Preparation of Zinc Hydroxide Carbonate\/Polymer Hybrids and Their Conversion into Zinc Oxide Thin\u2010Film Photocatalysts"],"prefix":"10.1002","volume":"22","author":[{"given":"Shunichi","family":"Matsumura","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biotechnology School of Engineering The University of Tokyo, Hongo, Bunkyo-ku  Tokyo 113-8656 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yoshimasa","family":"Horiguchi","sequence":"additional","affiliation":[{"name":"Department of 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