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These Zr\u2010NADC MOFs were constructed by using different mixtures of 2,6\u2010naphthalenedicarboxylate (NDC) and 4\u2010amino\u20102,6\u2010naphthalenedicarboxylate (NADC) as organic linkers. The fraction of NADC relative to NDC in these heterolinker MOFs ranges from 2 to 35\u2009%. The results indicate two competitive photoprocesses: NDC excimer formation and an energy transfer (ET) from excited NDC linkers to NADC linkers. Increasing the fraction of NADC linkers in the Zr\u2010NADC nanostructure decreases the mean time constant of NDC excimer formation, while the NADC emission intensity experiences a drop at the highest fraction of this linker in the MOF. The first observation is explained by an increase in the energy\u2010transfer probability between the two linkers, and the second by emission quenching in the NADC linkers due to ultrafast charge transfer assisted by the amino group. Femtosecond time\u2010resolved emission studies showed that the ET process (recorded as decaying and rising components) from excited NDC to NADC takes place in 1.2\u2005ps. Direct excitation of the NADC linkers (at 410\u2005nm) shows a decaying, but not rising, component of 250\u2013480\u2005fs, which could reflect the formation of a nonemissive charge\u2010separation state. The results show that by using MOFs having heterolinkers it is possible to trigger and tune excimer formation and ET processes.<\/jats:p>","DOI":"10.1002\/chem.201600669","type":"journal-article","created":{"date-parts":[[2016,7,12]],"date-time":"2016-07-12T08:59:52Z","timestamp":1468313992000},"page":"13072-13082","source":"Crossref","is-referenced-by-count":35,"title":["Competitive Excimer Formation and Energy Transfer in Zr\u2010Based Heterolinker Metal\u2013Organic Frameworks"],"prefix":"10.1002","volume":"22","author":[{"given":"Mario","family":"Guti\u00e9rrez","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica F\u00edsica Facultad de Ciencias Ambientales y Bioqu\u00edmica and INAMOL Universidad de Castilla-La Mancha  Avenida Carlos\u2005III, S.N. 45071 Toledo Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"F\u00e9lix","family":"S\u00e1nchez","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica Org\u00e1nica Consejo 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