{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T23:24:35Z","timestamp":1788996275215,"version":"build-2803163510"},"reference-count":44,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2016,3,15]],"date-time":"2016-03-15T00:00:00Z","timestamp":1458000000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100000848","name":"University of Edinburgh","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100000848","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2016,4,25]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We report the preparation of N\u2010heterocyclic carbene (NHC)\u2010stabilized compounds containing P=B double bonds. The reaction of the highly functionalized phosphinoborane Mes*(SiMe<jats:sub>3<\/jats:sub>)P\u2212B(Cl)Cp* with Lewis bases allows access to base\u2010stabilized phosphinidene boranes Mes*P=B(L)Cp* (L=4\u2010dimethylaminopyridine (DMAP), NHC) by Me<jats:sub>3<\/jats:sub>SiCl elimination. The formation of these species is shown to proceed through transient borylphosphide anions generated by Me<jats:sub>3<\/jats:sub>Si abstraction.<\/jats:p>","DOI":"10.1002\/chem.201600836","type":"journal-article","created":{"date-parts":[[2016,2,26]],"date-time":"2016-02-26T05:27:11Z","timestamp":1456464431000},"page":"6248-6252","source":"Crossref","is-referenced-by-count":43,"title":["Base\u2010Stabilized Phosphinidene Boranes by Silylium\u2010Ion Abstraction"],"prefix":"10.1002","volume":"22","author":[{"given":"Amy N.","family":"Price","sequence":"first","affiliation":[{"name":"EaStCHEM School of Chemistry University of Edinburgh  Edinburgh EH9 3FJ UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0664-2891","authenticated-orcid":false,"given":"Michael J.","family":"Cowley","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry University of Edinburgh  Edinburgh EH9 3FJ UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,3,15]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature08634"},{"key":"e_1_2_2_2_1","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1176443"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/b813442a"},{"key":"e_1_2_2_5_1","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja209215a"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305689"},{"key":"e_1_2_2_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201305689"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/om700365p"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00076-0"},{"key":"e_1_2_2_10_1","unstructured":"\u03c0-Bonds formed at planarized phosphorus are not inherently weaker than those formed by the nitrogen. The high inversion barrier at phosphorus makes their formation unfavourable. Thus iminoboranes are linear and phosphinidene boranes are expected to be bent. Also see ref. 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