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Reaction of <jats:bold>1<\/jats:bold> with ammonia\u2013borane resulted in transfer hydrogenolysis concomitantly with the cleavage of a P\u2212N bond. By treatment of <jats:bold>1<\/jats:bold> with 2,2,6,6\u2010tetramethylpiperidine\u20101\u2010oxyl (TEMPO), oxidation took place at one of the phosphorus atoms of <jats:bold>1<\/jats:bold>, and a P<jats:sup>V<\/jats:sup>\/P<jats:sup>III<\/jats:sup> mixed\u2010valence derivative was isolated. At the same time, it was demonstrated that only one of the phosphorus atoms in <jats:bold>1<\/jats:bold> behaves as an electron donor for electrophiles and Lewis acids. The former afforded an intramolecularly coordinated phosphine\u2010phosphenium species, whereas the latter demonstrates the ligand property of <jats:bold>1<\/jats:bold>. UV irradiation induced rearrangement of <jats:bold>1<\/jats:bold> into another example of another diazadiphosphapentalene.<\/jats:p>","DOI":"10.1002\/chem.201600935","type":"journal-article","created":{"date-parts":[[2016,6,10]],"date-time":"2016-06-10T06:10:08Z","timestamp":1465539008000},"page":"9976-9985","source":"Crossref","is-referenced-by-count":28,"title":["Reactivity Studies on a Diazadiphosphapentalene"],"prefix":"10.1002","volume":"22","author":[{"given":"Jingjing","family":"Cui","sequence":"first","affiliation":[{"name":"Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University  Nanyang Link 21 Singapore 637371 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongxin","family":"Li","sequence":"additional","affiliation":[{"name":"NTU-CBC Crystallography Facility Nanyang Technological University  Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rakesh","family":"Ganguly","sequence":"additional","affiliation":[{"name":"NTU-CBC Crystallography Facility Nanyang Technological University  Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rei","family":"Kinjo","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University  Nanyang Link 21 Singapore 637371 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,6,10]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2002-23535"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/9781847554529-00289"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.2174\/1568011013354543"},{"key":"e_1_2_6_5_2","doi-asserted-by":"crossref","first-page":"555","DOI":"10.2174\/1381612805666230110214512","volume":"5","author":"Colvin O. 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