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They reveal a single\u2010molecule magnet (SMM) behavior with a large zero direct current (dc) field energy barrier, \u0394<jats:italic>E<\/jats:italic>=266(12) cm<jats:sup>\u22121<\/jats:sup> (\u2248385\u2005K), originating from the single\u2010ion property of eight\u2010coordinated Dy<jats:sup>III<\/jats:sup> of an elongated dodecahedral geometry, which are embedded with diamagnetic [Co<jats:sup>III<\/jats:sup>(CN)<jats:sub>6<\/jats:sub>]<jats:sup>3\u2212<\/jats:sup> ions into zig\u2010zag coordination chains. The SMM character is enhanced by the external dc magnetic field, which results in the \u0394<jats:italic>E<\/jats:italic> of 320(23) cm<jats:sup>\u22121<\/jats:sup> (\u2248460\u2005K) at <jats:italic>H<\/jats:italic><jats:sub>dc<\/jats:sub>=1\u2005kOe, and the opening of a butterfly hysteresis loop below 6\u2005K. Complex <jats:bold>1<\/jats:bold> exhibits white Dy<jats:sup>III<\/jats:sup>\u2010based emission realized by energy transfer from Co<jats:sup>III<\/jats:sup> and 3\u2010OHpy to Dy<jats:sup>III<\/jats:sup>. Low temperature emission spectra were correlated with SMM property giving the estimation of the zero field \u0394<jats:italic>E<\/jats:italic>. <jats:bold>1<\/jats:bold> is a unique example of bifunctional magneto\u2010luminescent material combining white emission and slow magnetic relaxation with a large energy barrier, both controlled by rich structural and electronic interplay between Dy<jats:sup>III<\/jats:sup>, 3\u2010OHpy, and [Co<jats:sup>III<\/jats:sup>(CN)<jats:sub>6<\/jats:sub>]<jats:sup>3\u2212<\/jats:sup>.<\/jats:p>","DOI":"10.1002\/chem.201601244","type":"journal-article","created":{"date-parts":[[2016,3,19]],"date-time":"2016-03-19T03:20:52Z","timestamp":1458357652000},"page":"7371-7375","source":"Crossref","is-referenced-by-count":96,"title":["White Light Emissive Dy<sup>III<\/sup> Single\u2010Molecule Magnets Sensitized by Diamagnetic [Co<sup>III<\/sup>(CN)<sub>6<\/sub>]<sup>3\u2212<\/sup> Linkers"],"prefix":"10.1002","volume":"22","author":[{"given":"Szymon","family":"Chorazy","sequence":"first","affiliation":[{"name":"Department of Chemistry School of Science The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku  Tokyo 113-0033 Japan"},{"name":"Faculty of Chemistry Jagiellonian University  Ingardena 3 30-060 Krak\u00f3w Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Micha\u0142","family":"Rams","sequence":"additional","affiliation":[{"name":"Institute of Physics Jagiellonian University  \u0141ojasiewicza 11 30-348 Krak\u00f3w Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Koji","family":"Nakabayashi","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku  Tokyo 113-0033 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Barbara","family":"Sieklucka","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Ingardena 3 30-060 Krak\u00f3w Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shin\u2010ichi","family":"Ohkoshi","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku  Tokyo 113-0033 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,4,25]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200702876"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b501600m"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/nn401196a"},{"key":"e_1_2_2_5_1","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9061568"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm102388q"},{"key":"e_1_2_2_8_1","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2256"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/nphys3152"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604452"},{"key":"e_1_2_2_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604452"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja904156s"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202848"},{"key":"e_1_2_2_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201202848"},{"key":"e_1_2_2_15_1","unstructured":"\u00a0"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1067"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja508094h"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5084283"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/nphoton.2013.310"},{"key":"e_1_2_2_20_1","unstructured":"\u00a0"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0496423"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801810"},{"key":"e_1_2_2_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801810"},{"key":"e_1_2_2_23_2","first-page":"4622","author":"Yeo K. 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