{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,1]],"date-time":"2026-04-01T05:05:05Z","timestamp":1775019905961,"version":"3.50.1"},"reference-count":44,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2016,6,29]],"date-time":"2016-06-29T00:00:00Z","timestamp":1467158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000781","name":"European Research Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000781","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2016,9,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A 3D metal\u2013organic framework (MOF) having single\u2010molecule magnet (SMM) linkers was prepared in crystalline form by using a tetrairon(III) complex functionalised with two divergent pyridyl groups, namely [Fe<jats:sub>4<\/jats:sub>(pPy)<jats:sub>2<\/jats:sub>(dpm)<jats:sub>6<\/jats:sub>] (<jats:bold>1<\/jats:bold>; H<jats:sub>3<\/jats:sub>pPy=2\u2010(hydroxymethyl)\u20102\u2010(pyridin\u20104\u2010yl)propane\u20101,3\u2010diol, Hdpm=dipivaloylmethane). Reaction of <jats:bold>1<\/jats:bold> with silver(I) perchlorate afforded {[Fe<jats:sub>4<\/jats:sub>(pPy)<jats:sub>2<\/jats:sub>(dpm)<jats:sub>6<\/jats:sub>]<jats:sub>2<\/jats:sub>Ag}ClO<jats:sub>4<\/jats:sub> (<jats:bold>2<\/jats:bold>), which crystallises in a cubic face\u2010centred lattice and exhibits two interlocked diamondoid networks. In <jats:bold>2<\/jats:bold>, the SMMs act as linear ditopic synthons, and silver(I) ions as tetrahedral nodes coordinated by four pyridyl nitrogen atoms. The magnetic properties of <jats:bold>1<\/jats:bold> (<jats:italic>S<\/jats:italic>=5 and <jats:italic>D<\/jats:italic>\u2248\u22120.4\u2005cm<jats:sup>\u22121<\/jats:sup> in the ground spin state) are largely preserved in <jats:bold>2<\/jats:bold>, which shows slow magnetic relaxation with an anisotropy barrier of <jats:italic>U<\/jats:italic><jats:sub>eff<\/jats:sub>\/<jats:italic>k<\/jats:italic><jats:sub>B<\/jats:sub>=11.46(10)\u2005K in zero field and 14.25(8)\u2005K in an applied field of 1\u2005kOe. However, crystal symmetry triggers highly noncollinear magnetic anisotropy contributions oriented at 109.47\u00b0 from each other along the threefold axes of AgN<jats:sub>4<\/jats:sub> tetrahedra, a unique scenario fully confirmed by a single\u2010crystal cantilever torque magnetometry investigation. Magnetisation curves down to 0.03\u2005K demonstrated the occurrence of a wide hysteresis loop when the magnetic field was swept along one of the four Ag\u2212N bonds. By symmetry, the crystalline compound can then be persistently magnetised parallel or antiparallel to the four main diagonals of the unit cell, although the crystals have no overall second\u2010order anisotropy.<\/jats:p>","DOI":"10.1002\/chem.201601383","type":"journal-article","created":{"date-parts":[[2016,6,29]],"date-time":"2016-06-29T17:18:19Z","timestamp":1467220699000},"page":"13705-13714","source":"Crossref","is-referenced-by-count":22,"title":["Diamondoid Structure in a Metal\u2013Organic Framework of Fe<sub>4<\/sub> Single\u2010Molecule Magnets"],"prefix":"10.1002","volume":"22","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9875-9765","authenticated-orcid":false,"given":"Luca","family":"Rigamonti","sequence":"first","affiliation":[{"name":"Dipartimento di Scienze Chimiche e Geologiche Universit\u00e0 degli Studi di Modena e Reggio Emilia &amp; INSTM RU of Modena and Reggio Emilia  via G. Campi 103 41125 Modena Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Carri","family":"Cotton","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Chimiche e Geologiche Universit\u00e0 degli Studi di Modena e Reggio Emilia &amp; INSTM RU of Modena and Reggio Emilia  via G. Campi 103 41125 Modena Italy"},{"name":"Department of Chemistry University of Warwick, Gibbet Hill  Coventry CV4 7AL UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrea","family":"Nava","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Chimiche e Geologiche Universit\u00e0 degli Studi di Modena e Reggio Emilia &amp; INSTM RU of Modena and Reggio Emilia  via G. Campi 103 41125 Modena Italy"},{"name":"Dipartimento di Scienze Fisiche, Informatiche e Matematiche Universit\u00e0 degli Studi di Modena e Reggio Emilia  via G. Campi 213\/a 41125 Modena Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Heinrich","family":"Lang","sequence":"additional","affiliation":[{"name":"TU Chemnitz Fakult\u00e4t f\u00fcr Naturwissenschaften Institut f\u00fcr Chemie, Anorganische Chemie  Chemnitz 09107 Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tobias","family":"R\u00fcffer","sequence":"additional","affiliation":[{"name":"TU Chemnitz Fakult\u00e4t f\u00fcr Naturwissenschaften Institut f\u00fcr Chemie, Anorganische Chemie  Chemnitz 09107 Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mauro","family":"Perfetti","sequence":"additional","affiliation":[{"name":"Laboratory of Molecular Magnetism (LAMM) Dipartimento di Chimica \u2018Ugo Schiff' Universit\u00e0 degli Studi di Firenze &amp; INSTM RU of Firenze  via della Lastruccia 3\u201313 50019 Sesto Fiorentino (FI) Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4785-1331","authenticated-orcid":false,"given":"Lorenzo","family":"Sorace","sequence":"additional","affiliation":[{"name":"Laboratory of Molecular Magnetism (LAMM) Dipartimento di Chimica \u2018Ugo Schiff' Universit\u00e0 degli Studi di Firenze &amp; INSTM RU of Firenze  via della Lastruccia 3\u201313 50019 Sesto Fiorentino (FI) Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anne\u2010Laure","family":"Barra","sequence":"additional","affiliation":[{"name":"Laboratoire National des Champs Magn\u00e9tiques Intenses (LNCMI) CNRS  25 Avenue des Martyrs, BP 166 38042 Grenoble CEDEX 9 France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yanhua","family":"Lan","sequence":"additional","affiliation":[{"name":"Institut N\u00e9el CNRS  25 Avenue des Martyrs, BP 166 38042 Grenoble Cedex 9 France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wolfgang","family":"Wernsdorfer","sequence":"additional","affiliation":[{"name":"Institut N\u00e9el CNRS  25 Avenue des Martyrs, BP 166 38042 Grenoble Cedex 9 France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roberta","family":"Sessoli","sequence":"additional","affiliation":[{"name":"Laboratory of Molecular Magnetism (LAMM) Dipartimento di Chimica \u2018Ugo Schiff' Universit\u00e0 degli Studi di Firenze &amp; INSTM RU of Firenze  via della Lastruccia 3\u201313 50019 Sesto Fiorentino (FI) Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrea","family":"Cornia","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Chimiche e Geologiche Universit\u00e0 degli Studi di Modena e Reggio Emilia &amp; INSTM RU of Modena and Reggio Emilia  via G. 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