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The new compound underwent a variety of typical FLP reactions such as P\/B\u2010addition to the carbonyl group of <jats:italic>p<\/jats:italic>\u2010chloro\u2010benzaldehyde. Cooperative N,N\u2010addition to nitric oxide gave the respective persistent P\/B FLPNO<jats:sup>.<\/jats:sup> radical, which readily reacted with 1,4\u2010cyclohexadiene by H\u2010atom abstraction to yield the corresponding P\/B FLPNOH product. The B(Fxyl)<jats:sub>2<\/jats:sub>\u2010containing FLP reacted as a template for the HB(C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub> reduction of carbon monoxide to the formyl stage to give the respective FLP(\u03b7<jats:sup>2<\/jats:sup>\u2010formylborane) product. 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