{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T18:08:49Z","timestamp":1787162929327,"version":"build-2736575974"},"reference-count":76,"publisher":"Wiley","issue":"40","license":[{"start":{"date-parts":[[2016,7,19]],"date-time":"2016-07-19T00:00:00Z","timestamp":1468886400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"NSFC","doi-asserted-by":"crossref","award":["21025104"],"award-info":[{"award-number":["21025104"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"NSFC","doi-asserted-by":"crossref","award":["21271171"],"award-info":[{"award-number":["21271171"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"NSFC","doi-asserted-by":"crossref","award":["91022018"],"award-info":[{"award-number":["91022018"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2016,9,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Developing new methods to synthesize intermetallics is one of the most critical issues for the discovery and application of multifunctional metal materials; however, the synthesis of Sn\u2010containing intermetallics is challenging. In this work, we demonstrated for the first time that a self\u2010disproportionation\u2010induced in situ process produces cavernous Sn\u2212Cu intermetallics (Cu\n                    <jats:sub>3<\/jats:sub>\n                    Sn and Cu\n                    <jats:sub>6<\/jats:sub>\n                    Sn\n                    <jats:sub>5<\/jats:sub>\n                    ). The successful synthesis is realized by introducing inorganic metal salts (SnCl\n                    <jats:sub>2<\/jats:sub>\n                    <jats:bold>\u22c5<\/jats:bold>\n                    2\u2009H\n                    <jats:sub>2<\/jats:sub>\n                    O) to NaOH aqueous solution to form an intermediate product of reductant (Na\n                    <jats:sub>2<\/jats:sub>\n                    SnO\n                    <jats:sub>2<\/jats:sub>\n                    ) and by employing steam pressures that enhance the reduction ability. Distinct from the traditional in situ reduction, the current reduction process avoided the uncontrolled phase composition and excessive use of organic regents. An insight into the mechanism was revealed for the Sn\u2212Cu case. Moreover, this method could be extended to other Sn\u2010containing materials (Sn\u2212Co, Sn\u2212Ni). All these intermetallics were attempted in the catalytic effect on thermal decompositions of ammonium perchlorate. It is demonstrated that Cu\n                    <jats:sub>3<\/jats:sub>\n                    Sn showed an outstanding catalytic performance. The superior property might be primarily originated from the intrinsic chemical compositions and cavernous morphology as well. We supposed that this smart solution reduction methodology reported here would provide a new recognition for the reduction reaction, and its modified strategy may be applied to the synthesis of other metals, intermetallics as well as some unknown materials.\n                  <\/jats:p>","DOI":"10.1002\/chem.201601681","type":"journal-article","created":{"date-parts":[[2016,7,19]],"date-time":"2016-07-19T05:40:27Z","timestamp":1468906827000},"page":"14196-14204","source":"Crossref","is-referenced-by-count":7,"title":["Smart Solution Chemistry to Sn\u2010Containing Intermetallic Compounds through a Self\u2010Disproportionation Process"],"prefix":"10.1002","volume":"22","author":[{"given":"Yuelan","family":"Zhang","sequence":"first","affiliation":[{"name":"States Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University  Changchun 130012 P.R. China"},{"name":"Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of Matter  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liping","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of Matter  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of Matter  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianming","family":"Fan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of Matter  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Zheng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of Matter  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangshe","family":"Li","sequence":"additional","affiliation":[{"name":"States Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University  Changchun 130012 P.R. 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