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When the reaction was carried out in the presence of one equivalent of 2,2\u2032\u2010bipyridine, the adducts [M(CN)<jats:sub>3<\/jats:sub><jats:bold>\u22c5<\/jats:bold>(2,2\u2032\u2010bipy)] were obtained. The crystal structures of As(CN)<jats:sub>3<\/jats:sub>, [As(CN)<jats:sub>3<\/jats:sub><jats:bold>\u22c5<\/jats:bold>(2,2\u2032\u2010bipy)] and [Sb(CN)<jats:sub>3<\/jats:sub><jats:bold>\u22c5<\/jats:bold>(2,2\u2032\u2010bipy)] were determined and are surprisingly different. As(CN)<jats:sub>3<\/jats:sub> possesses a polymeric three\u2010dimensional structure, [As(CN)<jats:sub>3<\/jats:sub><jats:bold>\u22c5<\/jats:bold>(2,2\u2032\u2010bipy)] exhibits a two\u2010dimensional sheet structure, and [Sb(CN)<jats:sub>3<\/jats:sub><jats:bold>\u22c5<\/jats:bold>(2,2\u2032\u2010bipy)] has a chain structure, and none of the structures resembles those found for the corresponding arsenic and antimony triazides.<\/jats:p>","DOI":"10.1002\/chem.201602436","type":"journal-article","created":{"date-parts":[[2016,8,5]],"date-time":"2016-08-05T05:13:01Z","timestamp":1470373981000},"page":"13251-13257","source":"Crossref","is-referenced-by-count":13,"title":["Preparation and Characterization of Antimony and Arsenic Tricyanide and Their 2,2\u2032\u2010Bipyridine Adducts"],"prefix":"10.1002","volume":"22","author":[{"given":"Piyush","family":"Deokar","sequence":"first","affiliation":[{"name":"Loker Hydrocarbon Research Institute and Department of Chemistry University of Southern 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