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Herein, we report palladium\u2010catalyzed conditions for the N\u2010arylation of these ring systems. This protocol could be applied to a variety of (hetero)aryl chloride and bromide substrates, including ones, which are sterically hindered or those containing a variety of functional groups. Use of the fourth\u2010generation palladacycle precatalyst gave good to excellent yields by using low palladium\u2010catalyst loadings (0.1 to 1\u2005mol\u2009%).<\/jats:p>","DOI":"10.1002\/chem.201603449","type":"journal-article","created":{"date-parts":[[2016,8,3]],"date-time":"2016-08-03T09:46:16Z","timestamp":1470217576000},"page":"14186-14189","source":"Crossref","is-referenced-by-count":31,"title":["Palladium\u2010Catalyzed N\u2010Arylation of Iminodibenzyls and Iminostilbenes with Aryl\u2010 and Heteroaryl Halides"],"prefix":"10.1002","volume":"22","author":[{"given":"Wenliang","family":"Huang","sequence":"first","affiliation":[{"name":"Department of Chemistry Massachusetts Institute of Technology  77 Massachusetts Avenue Cambridge MA 02139 USA), Fax: (+1) 617 253-3297"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stephen L.","family":"Buchwald","sequence":"additional","affiliation":[{"name":"Department of Chemistry Massachusetts Institute of Technology  77 Massachusetts Avenue Cambridge MA 02139 USA), Fax: (+1) 617 253-3297"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,8,19]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200900281"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4TC01941E"},{"key":"e_1_2_2_4_1","unstructured":"\u00a0"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2007-979609"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1440-1819.1998.tb00966.x"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1014814924965"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1017\/S1461145704004651"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/nn1659"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/sj.bjp.0707253"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jocn.2007.04.010"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature07455"},{"key":"e_1_2_2_13_2","volume-title":"Strategies for Organic Drugs Synthesis and Design","author":"Lednicer D.","year":"2009"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/op900127v"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2013.12.035"},{"key":"e_1_2_2_16_1","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm980186p"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-4095(199810)10:14<1108::AID-ADMA1108>3.0.CO;2-S"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.10473"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm020414m"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/b506409k"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.3390\/ijms11010329"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.orgel.2011.01.020"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201300162"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.5b03238"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5TC03933A"},{"key":"e_1_2_2_27_1","unstructured":"\u00a0"},{"key":"e_1_2_2_28_2","first-page":"49","author":"Bo\u017einovi\u0107 N.","year":"2013","journal-title":"Synlett"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201100885"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2012.09.042"},{"key":"e_1_2_2_31_1","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja107511g"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201104363"},{"key":"e_1_2_2_33_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201104363"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol4030925"},{"key":"e_1_2_2_35_1","unstructured":"\u00a0"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/co2000289"},{"key":"e_1_2_2_37_2","first-page":"1181","author":"Chung K. 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