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With catalytic amounts of AgBF<jats:sub>4<\/jats:sub>, <jats:bold>2<\/jats:bold> was the major product. The reaction of <jats:bold>2<\/jats:bold> with [CuBr(SMe<jats:sub>2<\/jats:sub>)] (1:1) produced bromido\u2010bridged dimeric Cu<jats:sup>I<\/jats:sup> complex <jats:bold>5<\/jats:bold>. Molecular structures of compounds <jats:bold>3<\/jats:bold>, <jats:bold>4<\/jats:bold>, and <jats:bold>5<\/jats:bold> were obtained.<\/jats:p>","DOI":"10.1002\/chem.201603940","type":"journal-article","created":{"date-parts":[[2016,8,30]],"date-time":"2016-08-30T04:55:03Z","timestamp":1472532903000},"page":"15664-15668","source":"Crossref","is-referenced-by-count":14,"title":["Unusual Reactivity of Sodium Tetramesityltetraphosphanediide towards Cyclohexyl Isocyanide"],"prefix":"10.1002","volume":"22","author":[{"given":"Anup K.","family":"Adhikari","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry Universit\u00e4t Leipzig  Johannisallee 29 04103 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Menyh\u00e1rt B.","family":"S\u00e1rosi","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Universit\u00e4t Leipzig  Johannisallee 29 04103 Leipzig 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