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Toward some reagents it behaves similar to an intermolecular FLP; it cleaves dihydrogen, deprotonates terminal alkynes, and adds to organic carbonyl compounds including CO\n                    <jats:sub>2<\/jats:sub>\n                    . It shows typical intramolecular FLP reaction modes (cooperative 1,1\u2010additions) to mesityl azide, to carbon monoxide, and to NO. The latter reaction yields a persistent P\/B FLPNO nitroxide radical, which undergoes H\u2010atom abstraction reactions. The FLP\n                    <jats:bold>4<\/jats:bold>\n                    serves as a template for the CO reduction by [HB(C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] to generate a FLP\u2010\u03b7\n                    <jats:sup>2<\/jats:sup>\n                    \u2010formylborane. The formylborane moiety is removed from the FLP template by reaction with pyridine to yield a genuine pyridine stabilized formylborane that undergoes characteristic borane carbaldehyde reactions (Wittig olefination, imine formation). Most new products were characterized by X\u2010ray diffraction.\n                  <\/jats:p>","DOI":"10.1002\/chem.201603954","type":"journal-article","created":{"date-parts":[[2016,12,7]],"date-time":"2016-12-07T07:56:09Z","timestamp":1481097369000},"page":"6056-6068","source":"Crossref","is-referenced-by-count":69,"title":["The Chemistry of a Non\u2010Interacting Vicinal Frustrated Phosphane\/Borane Lewis Pair"],"prefix":"10.1002","volume":"23","author":[{"given":"Lisa\u2010Maria","family":"Elmer","sequence":"first","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gerald","family":"Kehr","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Constantin G.","family":"Daniliuc","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Melanie","family":"Siedow","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Physikalische Chemie Universut\u00e4t M\u00fcnster  Corrensstra\u00dfe 28\/30 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hellmut","family":"Eckert","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Physikalische Chemie Universut\u00e4t M\u00fcnster  Corrensstra\u00dfe 28\/30 48149 M\u00fcnster Germany"},{"name":"Instituto de F\u00edsica Sao Carlos Universidade de Sao Paulo  CP 369 13560-970 Sao Carlos, SP Brasil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"Tesch","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Armido","family":"Studer","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kamille","family":"Williams","sequence":"additional","affiliation":[{"name":"Georgetown University Department of Chemistry  Box 571227 Washington DC 20057-1227 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timothy H.","family":"Warren","sequence":"additional","affiliation":[{"name":"Georgetown University Department of Chemistry  Box 571227 Washington DC 20057-1227 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gerhard","family":"Erker","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,12,7]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409800"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409800"},{"key":"e_1_2_6_3_2","volume-title":"Frustrated Lewis Pairs I, Uncovering and Understanding","year":"2013"},{"key":"e_1_2_6_4_2","volume-title":"Frustrated Lewis Pairs II, Expanding the Scope, Topics Curr. 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