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Initially, a cascade carbonickelation\/MH reaction of 2\u2010cyanostyrenes was achieved using a key alkyne transfer hydrocyanation step. Mechanistic experiments supported the proposed catalytic cycle, including the turnover\u2010enabling transfer hydrocyanation step. The reactivity was then extended to the intermolecular MH reaction of benzonitriles and styrenes.<\/jats:p>","DOI":"10.1002\/chem.201604061","type":"journal-article","created":{"date-parts":[[2016,9,5]],"date-time":"2016-09-05T12:39:24Z","timestamp":1473079164000},"page":"15629-15633","source":"Crossref","is-referenced-by-count":47,"title":["Unlocking Mizoroki\u2013Heck\u2010Type Reactions of Aryl Cyanides Using Transfer Hydrocyanation as a Turnover\u2010Enabling Step"],"prefix":"10.1002","volume":"22","author":[{"given":"Xianjie","family":"Fang","sequence":"first","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peng","family":"Yu","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gabriele","family":"Prina\u2005Cerai","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3968-1424","authenticated-orcid":false,"given":"Bill","family":"Morandi","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,9,23]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00979a024"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.44.581"},{"key":"e_1_2_2_4_1","unstructured":"For reviews see:"},{"key":"e_1_2_2_5_2","first-page":"345","volume":"27","author":"Heck R. 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