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The compound was prepared by adopting a novel strategy for the corrole sulfonation, leading to the regioselective isomer in an almost quantitative yield. The phosphorus coordination has a key role in determining the corrole substitution pattern, limiting the formation of poly\u2010substituted species, which affected the reaction of the corrole free base. The resulting complex shows excellent optical properties in terms of emission quantum yield, also in polar protic solvents, including water. <jats:sup>31<\/jats:sup>P\u2005NMR spectroscopy in CD<jats:sub>3<\/jats:sub>OD indicates that the P sulfonate complex has been isolated in a hexacoordinated geometry with two different ligands (L1=\u2010OH, L2=\u2010OCH<jats:sub>3<\/jats:sub>), and it is prone to axial ligand exchange with methanol, with no evidence of intermediate pentacoordinated species. The morphological characterization of thin layers of the P corrole deposited onto an Au(111) surface showed that the addition of an intermediate layer of reduced graphene oxide allows for a better control of corrole aggregation, inducing also transformation of the Au(111) reconstructed surface.<\/jats:p>","DOI":"10.1002\/chem.201604233","type":"journal-article","created":{"date-parts":[[2016,10,27]],"date-time":"2016-10-27T07:22:57Z","timestamp":1477552977000},"page":"905-916","source":"Crossref","is-referenced-by-count":25,"title":["A Highly Emissive Water\u2010Soluble Phosphorus Corrole"],"prefix":"10.1002","volume":"23","author":[{"given":"Mario L.","family":"Naitana","sequence":"first","affiliation":[{"name":"Dipartimento di Scienze e Tecnologie Chimiche Universit\u00e0 di Roma \u201cTor Vergata\u201d  Via della Ricerca, Scientifica 1 00133 Rome Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3306-9293","authenticated-orcid":false,"given":"Sara","family":"Nardis","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze e Tecnologie Chimiche Universit\u00e0 di Roma \u201cTor Vergata\u201d  Via della Ricerca, Scientifica 1 00133 Rome Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Giuseppe","family":"Pomarico","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze e Tecnologie Chimiche Universit\u00e0 di Roma \u201cTor Vergata\u201d  Via della Ricerca, Scientifica 1 00133 Rome Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michele","family":"Raggio","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze e Tecnologie Chimiche Universit\u00e0 di Roma \u201cTor Vergata\u201d  Via della Ricerca, Scientifica 1 00133 Rome Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fabrizio","family":"Caroleo","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze e Tecnologie Chimiche Universit\u00e0 di Roma \u201cTor Vergata\u201d  Via della Ricerca, Scientifica 1 00133 Rome Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5012-1714","authenticated-orcid":false,"given":"Daniel O.","family":"Cicero","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze e Tecnologie Chimiche Universit\u00e0 di Roma \u201cTor Vergata\u201d  Via della Ricerca, Scientifica 1 00133 Rome Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9288-9155","authenticated-orcid":false,"given":"Sara","family":"Lentini","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze e Tecnologie Chimiche Universit\u00e0 di Roma \u201cTor Vergata\u201d  Via della Ricerca, Scientifica 1 00133 Rome Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1630-8291","authenticated-orcid":false,"given":"Luca","family":"Prodi","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica \u201cG. 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