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The new iodobromides show different structure motives yet are unknown from other nonahalides and can be better described as [(I<jats:sub>2<\/jats:sub>Br<jats:sub>3<\/jats:sub>)<jats:sup>\u2212<\/jats:sup>\u22c52\u2009IBr]. The additional IBr units are connected by halogen\u2013halogen interactions on the central V\u2010shaped [I<jats:sub>2<\/jats:sub>Br<jats:sub>3<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>. The characterization was performed by Raman spectroscopy and single crystal X\u2010ray structure determination. Conductivity measurements, thermogravimetric analysis and quantum\u2010chemical calculations completed the structural discussion.<\/jats:p>","DOI":"10.1002\/chem.201604392","type":"journal-article","created":{"date-parts":[[2016,10,26]],"date-time":"2016-10-26T12:23:36Z","timestamp":1477484616000},"page":"244-249","source":"Crossref","is-referenced-by-count":33,"title":["[NMe<sub>4<\/sub>][I<sub>4<\/sub>Br<sub>5<\/sub>]: A new Iodobromide from an Ionic Liquid with Halogen\u2013Halogen Interactions"],"prefix":"10.1002","volume":"23","author":[{"given":"Lisa","family":"Mann","sequence":"first","affiliation":[{"name":"Fachbereich Biologie, Chemie, Pharmazie Institut f\u00fcr Chemie und Biochemie\u2013Anorganische Chemie  Fabeckstra\u00dfe 34\/36 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrick","family":"Vo\u00dfnacker","sequence":"additional","affiliation":[{"name":"Fachbereich Biologie, Chemie, Pharmazie Institut f\u00fcr Chemie und Biochemie\u2013Anorganische Chemie  Fabeckstra\u00dfe 34\/36 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carsten","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Fachbereich Biologie, Chemie, Pharmazie Institut f\u00fcr Chemie und Biochemie\u2013Theoretische Chemie  Takustra\u00dfe 3 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebastian","family":"Riedel","sequence":"additional","affiliation":[{"name":"Fachbereich Biologie, Chemie, Pharmazie Institut f\u00fcr Chemie und Biochemie\u2013Anorganische Chemie  Fabeckstra\u00dfe 34\/36 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,11,25]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201400085"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1985-0111"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic000257y"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200800287"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201500370"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic201291k"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.5560\/znb.2013-3143"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201404505"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507948"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201507948"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201604348"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201604348"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39830000008"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00297a005"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20001103)39:21<3923::AID-ANIE3923>3.0.CO;2-Y"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20001103)112:21<4072::AID-ANGE4072>3.0.CO;2-M"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105237"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105237"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201100452"},{"key":"e_1_2_2_17_1","unstructured":"\u00a0"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic100869r"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2011.09.003"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19980216)37:3<293::AID-ANIE293>3.0.CO;2-5"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19980202)110:3<305::AID-ANGE305>3.0.CO;2-6"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19980202)110:3<305::AID-ANGE305>3.0.CO;2-6"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.73.61"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199807)624:7<1175::AID-ZAAC1175>3.0.CO;2-F"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305412"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201305412"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b00663"},{"key":"e_1_2_2_26_1","unstructured":"R. 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