{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T21:42:15Z","timestamp":1760305335244,"version":"build-2065373602"},"reference-count":34,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2016,11,23]],"date-time":"2016-11-23T00:00:00Z","timestamp":1479859200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,1,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>An organic polymer containing cyclobutanes and amides as backbones and pyridyl groups as sidearms was synthesized by single\u2010crystal\u2010to\u2010single\u2010crystal (SCSC) [2+2]\u2010photopolymerization in the coordination polymers (CPs) of diene. The diene molecule was photo\u2010inactive in its crystals and formed a triply intertwined 1D\u2010helical CP with Cd(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> and Cu(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> salts. The 1D\u2010CP was transformed into a coordination polymer of organic polymers containing threefold interpenetrated 3D\u2010networks of CdSO<jats:sub>4<\/jats:sub> topology through a [2+2]\u2010reaction in SCSC manner upon irradiation. The organic polymer was separated from its CPs and found to have an unusually high degree of polymerization for this type of reaction. Furthermore, the organic polymer was amenable for <jats:italic>N<\/jats:italic>\u2010alkylation reactions such as methylation, propylation, and decylation. The formate salts of the organic polymer and the methylated polymer were shown to form plastic films with a combination of properties such as high transparency, tensile strengths, gas permeability, thermal stability, water\u2010resistance, and resistance to other organic solvents. The methylated polymer was also able to capture chromate ions and anionic dyes from aqueous solutions.<\/jats:p>","DOI":"10.1002\/chem.201605067","type":"journal-article","created":{"date-parts":[[2016,11,8]],"date-time":"2016-11-08T04:56:42Z","timestamp":1478581002000},"page":"273-277","source":"Crossref","is-referenced-by-count":27,"title":["Water\u2010Resistant and Transparent Plastic Films from Functionalizable Organic Polymers: Coordination Polymers as Templates for Solid\u2010State [2+2]\u2010Photopolymerization"],"prefix":"10.1002","volume":"23","author":[{"given":"Mousumi","family":"Garai","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology  Kharagpur 721302 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5464-1952","authenticated-orcid":false,"given":"Kumar","family":"Biradha","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology  Kharagpur 721302 India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,11,23]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad4091"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201504786"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201504786"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00300"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar8001427"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja209792f"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0205333"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1265"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules16010119"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar700145r"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00040"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp802445r"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201300690"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201300690"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja409272p"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC08374E"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC00625A"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4cc02080d"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4cc00228h"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502179"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201502179"},{"key":"e_1_2_2_19_1","unstructured":"J.-g. Liu H.-j. Ni Z-h Wang S.-Y. Yang W.-F. Zhou Ch\u20053 InTech China 2015."},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b01299"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/mz500765y"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b05170"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc13994k"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0481981"},{"key":"e_1_2_2_25_1","unstructured":"The irradiation (approximately 96\u2005h) of1.Cu resulted in an amorphous material unlike1.Cd which was characterized by1H\u2005NMR spectroscopy. The appearance of new signals for cyclobutane protons at\u03b4=4.03 and 3.86\u2005ppm and the presence of olefin protons at\u03b4=7.60 and 6.93\u2005ppm confirm the formation of the polymer product with 60\u2009% yield (Figure\u2005S15 in the Supporting Information)."},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar3002624"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.5b01044"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2010.05.047"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.6b00381"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.6b01182"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc17441c"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201605067","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201605067","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T21:03:35Z","timestamp":1760303015000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201605067"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,11,23]]},"references-count":34,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2017,1,5]]}},"alternative-id":["10.1002\/chem.201605067"],"URL":"https:\/\/doi.org\/10.1002\/chem.201605067","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2016,11,23]]}}}