{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,19]],"date-time":"2026-06-19T02:13:44Z","timestamp":1781835224789,"version":"3.54.5"},"reference-count":187,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2016,12,23]],"date-time":"2016-12-23T00:00:00Z","timestamp":1482451200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,1,23]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We describe ferrocene\u2010based N\u2010heterocyclic germylenes and stannylenes of the type [Fe{(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>)NR}<jats:sub>2<\/jats:sub>E:] (<jats:bold>1\u2009R<\/jats:bold>E; E=Ge, Sn; R=neopentyl (Np), mesityl (Mes), trimethylsilyl (TMS)), which constitute the first examples of redox\u2010functionalised N\u2010heterocyclic tetrylenes (NHTs). These compounds are thermally stable and were structurally characterised by means of X\u2010ray diffraction studies, except for the neopentyl\u2010substituted stannylene <jats:bold>1\u2009Np<\/jats:bold>Sn, the decomposition of which afforded the aminoiminoferrocene [fc(NHCH<jats:sub>2<\/jats:sub><jats:italic>t<\/jats:italic>Bu)(N=CH<jats:italic>t<\/jats:italic>Bu)] (<jats:bold>2<\/jats:bold>) and the spiro tin(IV) compound (<jats:bold>1\u2009Np<\/jats:bold>)<jats:sub>2<\/jats:sub>Sn (<jats:bold>3<\/jats:bold>). DFT calculations show that the HOMO of the NHTs of our study is localised on the ferrocenylene backbone. A one\u2010electron oxidation process affords ions of the type <jats:bold>1\u2009R<\/jats:bold>E<jats:sup>+.<\/jats:sup>. In contrast to the NHC system <jats:bold>1\u2009R<\/jats:bold>C, the localised ferrocenium\u2010type nature of the oxidised form does not compromise the fundamental tetrylene character of <jats:bold>1\u2009R<\/jats:bold>E<jats:sup>+.<\/jats:sup>.<\/jats:p>","DOI":"10.1002\/chem.201605074","type":"journal-article","created":{"date-parts":[[2016,11,17]],"date-time":"2016-11-17T09:27:02Z","timestamp":1479374822000},"page":"1187-1199","source":"Crossref","is-referenced-by-count":63,"title":["Redox\u2010Active N\u2010Heterocyclic Germylenes and Stannylenes with a Ferrocene\u20101,1\u2032\u2010diyl Backbone"],"prefix":"10.1002","volume":"23","author":[{"given":"Jan","family":"Oetzel","sequence":"first","affiliation":[{"name":"Institute of Chemistry University of Kassel  Heinrich-Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nadine","family":"Weyer","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Kassel  Heinrich-Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Clemens","family":"Bruhn","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Kassel  Heinrich-Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Leibold","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Kassel  Heinrich-Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Birgit","family":"Gerke","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie Universit\u00e4t M\u00fcnster  Corrensstrasse 30 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rainer","family":"P\u00f6ttgen","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie Universit\u00e4t M\u00fcnster  Corrensstrasse 30 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Markus","family":"Maier","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Universit\u00e4t Konstanz  Universit\u00e4tsstrasse 10 78453 Konstanz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rainer F.","family":"Winter","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Universit\u00e4t Konstanz  Universit\u00e4tsstrasse 10 78453 Konstanz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Max. C.","family":"Holthausen","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganisch und Analytische Chemie Johann Wolfgang Goethe-Universit\u00e4t Frankfurt  Max-von-Laue-Strasse 7 60438 Frankfurt am Main Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ulrich","family":"Siemeling","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Kassel  Heinrich-Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,12,23]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature13384"},{"key":"e_1_2_6_2_1","unstructured":"See for example:"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1515\/revic-2013-0014"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900093s"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01743"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/om5012616"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00085a088"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00001a054"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00829a086"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C39740000895"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1982-1103"},{"key":"e_1_2_6_12_1","unstructured":"Selected recent reviews:"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_6_14_2","first-page":"279","volume-title":"Metal Amide Chemistry","author":"Lappert M.","year":"2009"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200800866"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/om7007869"},{"key":"e_1_2_6_17_1","unstructured":"Recent reviews:"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.02.011"},{"key":"e_1_2_6_19_2","first-page":"1045","author":"Mo Z.","year":"2014","journal-title":"Synlett"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2013.09.036"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201200443"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100990"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/c002475a"},{"key":"e_1_2_6_24_1","unstructured":"For recent examples see:"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506269"},{"key":"e_1_2_6_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201506269"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc42424c"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/om400348h"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja304067k"},{"key":"e_1_2_6_29_1","unstructured":"For recent examples see:"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.6b00517"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt51278a"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201301247"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja102686u"},{"key":"e_1_2_6_34_1","unstructured":"For recent reviews on switchable catalysts see:"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00426"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00096C"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500613"},{"key":"e_1_2_6_38_1","unstructured":"\u00a0"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b01064"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3DT52669K"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200900863"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1039\/B813809E"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704978"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704978"},{"key":"e_1_2_6_44_1","doi-asserted-by":"crossref","unstructured":"F. 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