{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T15:27:21Z","timestamp":1789226841686,"version":"build-2803163510"},"reference-count":107,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2016,12,9]],"date-time":"2016-12-09T00:00:00Z","timestamp":1481241600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,1,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The known procedures for the conversion of alkenylstannanes into the corresponding fluoroalkenes suffer from largely variable yields and a limited compatibility with functional groups; most notably, protodestannation becomes a serious issue whenever protic sites are present in the substrate. Outlined in this paper is a convenient alternative with a much improved application profile, which is largely unperturbed by free alcohols and amides of all sorts. Key to success is the use of F\u2010TEDA\u2010PF<jats:sub>6<\/jats:sub> in combination with non\u2010hygroscopic and bench\u2010stable silver phosphinate (AgOP(O)Ph<jats:sub>2<\/jats:sub>) that acts as an essentially neutral, non\u2010nucleophilic promotor and effective tin\u2010scavenger at the same time. This new method opens many opportunities for late\u2010stage fluorination of elaborate compounds far beyond the scope of the literature procedures, as witnessed by the preparation of a fluorinated macrolide antibiotic, a fluorinated prostaglandin derivative, and a set of fluorinated amino acid surrogates and peptide isosteres.<\/jats:p>","DOI":"10.1002\/chem.201605444","type":"journal-article","created":{"date-parts":[[2016,11,24]],"date-time":"2016-11-24T06:42:51Z","timestamp":1479969771000},"page":"558-562","source":"Crossref","is-referenced-by-count":54,"title":["Stereospecific Synthesis of Fluoroalkenes by Silver\u2010Mediated Fluorination of Functionalized Alkenylstannanes"],"prefix":"10.1002","volume":"23","author":[{"given":"Heiko","family":"Sommer","sequence":"first","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  45470 M\u00fclheim\/Ruhr Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alois","family":"F\u00fcrstner","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  45470 M\u00fclheim\/Ruhr Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,12,9]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201311080"},{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201311080"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b01475"},{"key":"e_1_2_2_3_1","unstructured":"For reviews on alkynetrans-hydrometalation see:"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2005-861874"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20150317"},{"key":"e_1_2_2_6_1","unstructured":"For relatedtrans-addition reactions see:"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201205946"},{"key":"e_1_2_2_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201205946"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307584"},{"key":"e_1_2_2_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201307584"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411618"},{"key":"e_1_2_2_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201411618"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506075"},{"key":"e_1_2_2_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201506075"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402719"},{"key":"e_1_2_2_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201402719"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201501608"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201501608"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b01431"},{"key":"e_1_2_2_14_1","doi-asserted-by":"crossref","unstructured":"S. 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