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The corresponding monooxidation products Ph<jats:sub>2<\/jats:sub>P(X)\u2010BH<jats:sub>2<\/jats:sub>\u22c5NMe<jats:sub>3<\/jats:sub> (X=O\u2013Te, <jats:bold>3\u2009a<\/jats:bold>\u2013<jats:bold>d<\/jats:bold>) and <jats:italic>t<\/jats:italic>BuHP(X)\u2010BH<jats:sub>2<\/jats:sub>\u22c5NMe<jats:sub>3<\/jats:sub> (X=O\u2013Te, <jats:bold>4\u2009a<\/jats:bold>\u2013<jats:bold>d<\/jats:bold>) were obtained in good yields and comprehensively characterized by single crystal X\u2010ray structure analysis, NMR, IR spectroscopy and mass spectrometry. The first oxidation step proceeds very selectively for all chalcogenides. For the <jats:italic>t<\/jats:italic>Bu derivative, a further oxidation can be realised with O<jats:sub>2<\/jats:sub>, S<jats:sub>8<\/jats:sub> and Se yielding <jats:italic>t<\/jats:italic>Bu(HX)P(X)\u2010BH<jats:sub>2<\/jats:sub>\u22c5NMe<jats:sub>3<\/jats:sub> (X=O, S, Se, <jats:bold>5\u2009a<\/jats:bold>\u2013<jats:bold>c<\/jats:bold>). The telluride compounds presented herein are the first examples of neutral Te\u2010substituted phosphanylboranes.<\/jats:p>","DOI":"10.1002\/chem.201605625","type":"journal-article","created":{"date-parts":[[2017,1,24]],"date-time":"2017-01-24T15:43:24Z","timestamp":1485272604000},"page":"4397-4404","source":"Crossref","is-referenced-by-count":18,"title":["Oxidation of Substituted Phosphanylboranes with Chalcogens"],"prefix":"10.1002","volume":"23","author":[{"given":"Christian","family":"Marquardt","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Regensburg  93040 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Oliver","family":"Hegen","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Regensburg  93040 Regensburg 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