{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,23]],"date-time":"2025-10-23T11:12:20Z","timestamp":1761217940847,"version":"build-2065373602"},"reference-count":67,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2017,5,8]],"date-time":"2017-05-08T00:00:00Z","timestamp":1494201600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["61474124","21420102006"],"award-info":[{"award-number":["61474124","21420102006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,5,29]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Honeycomb\u2010structured films represent an intriguing class of two\u2010dimensional porous materials. Specifically, polyoxometalate (POM) macroanions can be introduced into these films by complexing with oppositely charged, double\u2010tailed surfactants. Here highly\u2010ordered honeycomb structures are reported that can be constructed by the complexes between POMs and a room temperature ionic liquid (<jats:bold>IL1<\/jats:bold>) having an imidazolium moiety in the middle and a naphthyl unit and a branched aliphatic chain at the ends. The complexes can be produced through phase transfer between an aqueous solution of POMs (typically {Mo<jats:sub>72<\/jats:sub>Fe<jats:sub>30<\/jats:sub>}) and a CS<jats:sub>2<\/jats:sub> (or chloroform) solution of <jats:bold>IL1<\/jats:bold>. Based on the intrinsic properties of {Mo<jats:sub>72<\/jats:sub>Fe<jats:sub>30<\/jats:sub>} and the functional groups of the <jats:bold>IL1<\/jats:bold>, the honeycomb structures show multiple functions with bright photoluminescence and rich electrochemical properties. This work shows that by simply engineering the organic ligands involved in the POM\u2010based inorganic\u2013organic complexes, supramolecular structures with improved properties and wide applications can be obtained.<\/jats:p>","DOI":"10.1002\/chem.201605651","type":"journal-article","created":{"date-parts":[[2017,3,29]],"date-time":"2017-03-29T10:55:32Z","timestamp":1490784932000},"page":"7278-7286","source":"Crossref","is-referenced-by-count":10,"title":["Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium\u2010Based Ionic Liquid Bearing a \u03c0\u2010Conjugated Moiety and a Branched Aliphatic Chain"],"prefix":"10.1002","volume":"23","author":[{"given":"Geping","family":"Zhang","sequence":"first","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry &amp; Key Laboratory of Special Aggregated Materials Ministry of Education Shandong University  Jinan 250100 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hongxia","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry &amp; Key Laboratory of Special Aggregated Materials Ministry of Education Shandong University  Jinan 250100 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mengjun","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry &amp; Key Laboratory of Special Aggregated Materials Ministry of Education Shandong University  Jinan 250100 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hongguang","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solid Lubrication, Laboratory of Clean Energy Chemistry and Materials Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ye","family":"Yuan","sequence":"additional","affiliation":[{"name":"Taishan College Shandong University  Jinan 250100 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tiantai","family":"Ma","sequence":"additional","affiliation":[{"name":"Taishan College Shandong University  Jinan 250100 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jingcheng","family":"Hao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry &amp; Key Laboratory of Special Aggregated Materials Ministry of Education Shandong University  Jinan 250100 P. R. 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