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Their crystal structures were determined by single\u2010crystal XRD techniques. Thin films of these compounds were first successfully deposited on indium tin oxide (ITO) glass through one\u2010step electrophoretic deposition under mild conditions. The europium CSN film exhibits intense red emission and can act as a highly sensitive luminescent sensor for H<jats:sub>2<\/jats:sub>PO<jats:sub>4<\/jats:sub><jats:sup>\u2212<\/jats:sup> anions and adenosine triphosphate (ATP) in aqueous solution. The limits of detection of H<jats:sub>2<\/jats:sub>PO<jats:sub>4<\/jats:sub><jats:sup>\u2212<\/jats:sup> and ATP can achieve 0.68 and 1.9\u2005\u03bc<jats:sc>m<\/jats:sc> respectively. The sensing mechanism was further explored through fluorescence and UV techniques. The fabricated sensor also showed excellent selectivity towards these phosphates in the presence of other coexisting ions (F<jats:sup>\u2212<\/jats:sup>, Cl<jats:sup>\u2212<\/jats:sup>, Br<jats:sup>\u2212<\/jats:sup>, I<jats:sup>\u2212<\/jats:sup>, SO<jats:sub>4<\/jats:sub><jats:sup>\u2212<\/jats:sup>, CO<jats:sub>3<\/jats:sub><jats:sup>2\u2212<\/jats:sup>, NO<jats:sub>3<\/jats:sub><jats:sup>\u2212<\/jats:sup>, and AcO<jats:sup>\u2212<\/jats:sup>) without interference. Moreover, we demonstrated the feasibility of using this sensor to detect ATP in bovine serum samples, suggesting the potential value of application in real biosystems.<\/jats:p>","DOI":"10.1002\/chem.201700114","type":"journal-article","created":{"date-parts":[[2017,4,5]],"date-time":"2017-04-05T15:00:33Z","timestamp":1491404433000},"page":"7748-7754","source":"Crossref","is-referenced-by-count":22,"title":["A Novel Electrophoretic Deposited Coordination Supramolecular Network Film for Detecting Phosphate and Biophosphate"],"prefix":"10.1002","volume":"23","author":[{"given":"Tianshu","family":"Chu","sequence":"first","affiliation":[{"name":"School of Materials Science &amp; Engineering School of Chemistry and Chemical Engineering Sun Yat-Sen University  Guangzhou 510275 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Feng","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering School of Chemistry and Chemical Engineering Sun Yat-Sen University  Guangzhou 510275 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yi","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering School of Chemistry and Chemical Engineering Sun Yat-Sen University  Guangzhou 510275 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yangyi","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering School of Chemistry and Chemical Engineering Sun Yat-Sen University  Guangzhou 510275 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Seik Weng","family":"Ng","sequence":"additional","affiliation":[{"name":"Chemistry Department Faculty of Science King Abdulaziz University, PO Box 80203  Jeddah Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,5,19]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1031"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08008"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500632f"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC10195F"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b10130"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00022J"},{"key":"e_1_2_7_9_1","unstructured":"\u00a0"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2201"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja101937w"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1CC16066D"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0704784"},{"key":"e_1_2_7_15_1","unstructured":"\u00a0"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/om2000019"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm060757a"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.200900371"},{"key":"e_1_2_7_19_1","unstructured":"\u00a0"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4TC02369B"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/la9033244"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200502138"},{"key":"e_1_2_7_23_1","unstructured":"\u00a0"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200802490"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4TC00689E"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ta11925d"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201401940"},{"key":"e_1_2_7_28_1","unstructured":"\u00a0"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602006"},{"key":"e_1_2_7_29_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200602006"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo201290a"},{"key":"e_1_2_7_31_1","unstructured":"\u00a0"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/c000542h"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3pp50105a"},{"key":"e_1_2_7_34_1","unstructured":"\u00a0"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg100843k"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ce25075f"},{"key":"e_1_2_7_37_1","unstructured":"A.\u2005L. 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