{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T23:52:45Z","timestamp":1785196365122,"version":"3.55.0"},"reference-count":82,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2017,2,20]],"date-time":"2017-02-20T00:00:00Z","timestamp":1487548800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100003329","name":"Ministerio de Econom\u00eda y Competitividad","doi-asserted-by":"publisher","award":["CTQ2013-44625-R"],"award-info":[{"award-number":["CTQ2013-44625-R"]}],"id":[{"id":"10.13039\/501100003329","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006302","name":"Universidad de Alcal\u00e1","doi-asserted-by":"publisher","award":["CCG2015\/EXP-026"],"award-info":[{"award-number":["CCG2015\/EXP-026"]}],"id":[{"id":"10.13039\/501100006302","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,3,13]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Simple exposure of a hexane solution of [TiCp*Me<jats:sub>3<\/jats:sub>] (Cp*=\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>Me<jats:sub>5<\/jats:sub>) to an atmosphere of commercially available and inexpensive forming gas (H<jats:sub>2<\/jats:sub>\/N<jats:sub>2<\/jats:sub> mixture, 13.5\u201316.5\u2009% of H<jats:sub>2<\/jats:sub>) at room temperature leads to the methylidene\u2013methylidyne\u2013nitrido cube\u2010type complex [(TiCp*)<jats:sub>4<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010CH)(\u03bc<jats:sub>3<\/jats:sub>\u2010CH<jats:sub>2<\/jats:sub>)(\u03bc<jats:sub>3<\/jats:sub>\u2010N)<jats:sub>2<\/jats:sub>] via dinitrogen cleavage. This paramagnetic compound reacts with [D<jats:sub>1<\/jats:sub>]chloroform to give the titanium(IV) methylidyne\u2013nitrido species [(TiCp*)<jats:sub>4<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010CH)<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010N)<jats:sub>2<\/jats:sub>], whereas its one\u2010electron oxidation with AgOTf or [Fe(\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>](OTf) (OTf=O<jats:sub>3<\/jats:sub>SCF<jats:sub>3<\/jats:sub>) yields the diamagnetic ionic derivative [(TiCp*)<jats:sub>4<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010CH)(\u03bc<jats:sub>3<\/jats:sub>\u2010CH<jats:sub>2<\/jats:sub>)(\u03bc<jats:sub>3<\/jats:sub>\u2010N)<jats:sub>2<\/jats:sub>](OTf). The \u03bc<jats:sub>3<\/jats:sub>\u2010nitrido ligands of the methylidyne\u2013nitrido cubane complex can be protonated with [LutH](OTf) (Lut=2,6\u2010lutidine) or hydrogenated with NH<jats:sub>3<\/jats:sub><jats:bold>\u22c5<\/jats:bold>BH<jats:sub>3<\/jats:sub> to afford \u03bc<jats:sub>3<\/jats:sub>\u2010NH imido moieties.<\/jats:p>","DOI":"10.1002\/chem.201700152","type":"journal-article","created":{"date-parts":[[2017,2,2]],"date-time":"2017-02-02T14:10:01Z","timestamp":1486044601000},"page":"3558-3561","source":"Crossref","is-referenced-by-count":21,"title":["Cleavage of Dinitrogen from Forming Gas by a Titanium Molecular System under Ambient Conditions"],"prefix":"10.1002","volume":"23","author":[{"given":"Mariano","family":"Gonz\u00e1lez\u2010Moreiras","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica y Qu\u00edmica Inorg\u00e1nica Universidad de Alcal\u00e1  28805 Alcal\u00e1 de Henares-Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7456-1212","authenticated-orcid":false,"given":"Miguel","family":"Mena","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica y Qu\u00edmica Inorg\u00e1nica Universidad de Alcal\u00e1  28805 Alcal\u00e1 de Henares-Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0086-8825","authenticated-orcid":false,"given":"Adri\u00e1n","family":"P\u00e9rez\u2010Redondo","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica y Qu\u00edmica Inorg\u00e1nica Universidad de Alcal\u00e1  28805 Alcal\u00e1 de Henares-Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0425-4799","authenticated-orcid":false,"given":"Carlos","family":"Y\u00e9lamos","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica y Qu\u00edmica Inorg\u00e1nica Universidad de Alcal\u00e1  28805 Alcal\u00e1 de Henares-Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,2,20]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"For selected recent reviews see:"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ic90033e"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2013.02.010"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00085D"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2013.11.024"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b00881"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00033"},{"key":"e_1_2_2_8_1","unstructured":"For original references and a recent book on the industrial synthesis of ammonia 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However the identity of the bridging ligands cannot be unambiguously established from the crystallographic data and we are currently investigating the reactivity of this compound to gain information into its composition."},{"key":"e_1_2_2_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b13323"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201700152","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201700152","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.201700152","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201700152","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T20:41:36Z","timestamp":1760301696000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201700152"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,2,20]]},"references-count":82,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2017,3,13]]}},"alternative-id":["10.1002\/chem.201700152"],"URL":"https:\/\/doi.org\/10.1002\/chem.201700152","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,2,20]]}}}