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The 2,2\u2032\u2010bipyridine (bipy) adducts [(bipy)<jats:sub>2<\/jats:sub>Ga(CN)<jats:sub>2<\/jats:sub>][Ga(CN)<jats:sub>4<\/jats:sub>], [(bipy)In(CN)<jats:sub>3<\/jats:sub>], and [(bipy)Tl(CN)<jats:sub>3<\/jats:sub>] were obtained from the reaction of MF<jats:sub>3<\/jats:sub> with Me<jats:sub>3<\/jats:sub>SiCN and bipy in acetonitrile. While the reaction of the metal trifluorides with Me<jats:sub>3<\/jats:sub>SiCN in acetonitrile resulted in recovery of the starting materials, the reaction of MF<jats:sub>3<\/jats:sub> with Me<jats:sub>3<\/jats:sub>SiCN in pyridine (py) solution resulted in the formation of the pyridine adducts [(py)<jats:sub>2<\/jats:sub>Ga(CN)<jats:sub>3<\/jats:sub>], [(py)<jats:sub>3<\/jats:sub>In(CN)<jats:sub>3<\/jats:sub>], and [(py)<jats:sub>2<\/jats:sub>Tl(CN)<jats:sub>3<\/jats:sub>]. The cyano compounds were characterized by their vibrational spectra and, in most cases, by their X\u2010ray crystal structures.<\/jats:p>","DOI":"10.1002\/chem.201700611","type":"journal-article","created":{"date-parts":[[2017,4,4]],"date-time":"2017-04-04T21:20:42Z","timestamp":1491340842000},"page":"9054-9066","source":"Crossref","is-referenced-by-count":9,"title":["Preparation and Characterization of Group\u200513 Cyanides"],"prefix":"10.1002","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4151-3593","authenticated-orcid":false,"given":"Ralf","family":"Haiges","sequence":"first","affiliation":[{"name":"Loker Hydrocarbon Research Institute and Department of Chemistry University of Southern California  Los Angeles CA 90089 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Piyush","family":"Deokar","sequence":"additional","affiliation":[{"name":"Loker Hydrocarbon Research Institute and Department of Chemistry University of Southern California  Los Angeles CA 90089 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Monica","family":"Vasiliu","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Alabama  Tuscaloosa AL 35487 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Trent H.","family":"Stein","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Alabama  Tuscaloosa AL 35487 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"David A.","family":"Dixon","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Alabama  Tuscaloosa AL 35487 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0661-5519","authenticated-orcid":false,"given":"Karl O.","family":"Christe","sequence":"additional","affiliation":[{"name":"Loker Hydrocarbon Research Institute and Department of Chemistry University of Southern California  Los Angeles CA 90089 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,5,19]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00320"},{"key":"e_1_2_8_3_2","unstructured":"Y.Lu L.Wang S.Vail J.-J.Lee Sharp Laboratories of America Inc. 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