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Furthermore, the phosphorus(V)sulfide derivative of\n                    <jats:bold>PN4<\/jats:bold>\n                    was synthesized to get additional structural information in the solid state. Two mononuclear gold complexes [(\n                    <jats:bold>PN4<\/jats:bold>\n                    )AuCl] and [(\n                    <jats:bold>PN4<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    Au]ClO\n                    <jats:sub>4<\/jats:sub>\n                    were synthesized first. Then, the two hetero trimetallic gold complexes [(\n                    <jats:bold>PN4<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    AuAg\n                    <jats:sub>2<\/jats:sub>\n                    ](OTf)\n                    <jats:sub>3<\/jats:sub>\n                    (Tf=triflate) and [(\n                    <jats:bold>PN4<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    AuCu\n                    <jats:sub>2<\/jats:sub>\n                    ](OTf)\n                    <jats:sub>3<\/jats:sub>\n                    were synthesized by selectively filling the bipyridine coordination compartments with the lighter coinage metals. For comparison two trinuclear silver complexes, that is, [(\n                    <jats:bold>PN4<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    Ag\n                    <jats:sub>3<\/jats:sub>\n                    ]OTf and [(\n                    <jats:bold>PN4<\/jats:bold>\n                    )(py)\n                    <jats:sub>2<\/jats:sub>\n                    Ag\n                    <jats:sub>3<\/jats:sub>\n                    (\u03bc\u2010Cl)(\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    \u2010Cl)]ClO\n                    <jats:sub>4<\/jats:sub>\n                    (py=pyridine) were prepared. All compounds were fully characterized including single\u2010crystal X\u2010ray diffraction,\n                    <jats:sup>15<\/jats:sup>\n                    N,\n                    <jats:sup>19<\/jats:sup>\n                    F and\n                    <jats:sup>109<\/jats:sup>\n                    Ag\u2005NMR spectroscopy. The photophysical properties of the new compounds were determined in the solid state. These revealed a different behavior between the Au\u2013Cu and Au\u2013Ag\/Ag\u2013Ag compounds. [(\n                    <jats:bold>PN4<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    AuAg\n                    <jats:sub>2<\/jats:sub>\n                    ](OTf)\n                    <jats:sub>3<\/jats:sub>\n                    was found to be the brightest emitter. Time\u2010dependent density functional calculations were performed to illuminate the differences in the photophysical properties.\n                  <\/jats:p>","DOI":"10.1002\/chem.201701091","type":"journal-article","created":{"date-parts":[[2017,5,2]],"date-time":"2017-05-02T11:28:06Z","timestamp":1493724486000},"page":"12198-12209","source":"Crossref","is-referenced-by-count":20,"title":["Bis(6\u2010methylene\u20102,2\u2032\u2010bipyridine)phenylphosphine\u2014A Flexible Ligand for the Construction of Trinuclear Coinage\u2010Metal Complexes"],"prefix":"10.1002","volume":"23","author":[{"given":"Sebastian","family":"Sch\u00e4fer","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Engesserstra\u00dfe 15 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael T.","family":"Gamer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Engesserstra\u00dfe 15 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergei","family":"Lebedkin","sequence":"additional","affiliation":[{"name":"Institute of Nanotechnology Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz 1 76344 Eggenstein-Leopoldshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Florian","family":"Weigend","sequence":"additional","affiliation":[{"name":"Institute of Nanotechnology Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz 1 76344 Eggenstein-Leopoldshafen Germany"},{"name":"Institute of Physical Chemistry Karlsruhe Institute of Technology (KIT)  Fritz-Haber Weg 2 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred M.","family":"Kappes","sequence":"additional","affiliation":[{"name":"Institute of Nanotechnology Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz 1 76344 Eggenstein-Leopoldshafen Germany"},{"name":"Institute of Physical Chemistry Karlsruhe Institute of Technology (KIT)  Fritz-Haber Weg 2 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0915-3893","authenticated-orcid":false,"given":"Peter W.","family":"Roesky","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Engesserstra\u00dfe 15 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,6]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198815441"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19881001130"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/b708845k"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15182G"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201405936"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201405936"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/om501125c"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199106041"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911030542"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar50140a002"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/a804249g"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/b708615f"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.11.015"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.01.017"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc13767k"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2011.02.003"},{"key":"e_1_2_7_14_1","doi-asserted-by":"crossref","first-page":"1321","DOI":"10.1351\/PAC-CON-12-11-19","volume":"85","author":"Yam Vivian W.-W.","year":"2013","journal-title":"Pure Appl. 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