{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T01:17:16Z","timestamp":1789780636817,"version":"4.0.1"},"reference-count":97,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2017,6,23]],"date-time":"2017-06-23T00:00:00Z","timestamp":1498176000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["Sche 384\/32-1"],"award-info":[{"award-number":["Sche 384\/32-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A detailed method for the preparation of [Cp\u2032\u2032<jats:sub>2<\/jats:sub>Zr(\u03b7<jats:sup>1:1<\/jats:sup>\u2010P<jats:sub>4<\/jats:sub>)] (<jats:bold>1<\/jats:bold>) is presented. The coordination behavior of <jats:bold>1<\/jats:bold> towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe<jats:sub>3<\/jats:sub>, AlEt<jats:sub>3<\/jats:sub>) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X\u2010ray structural analysis.<\/jats:p>","DOI":"10.1002\/chem.201701380","type":"journal-article","created":{"date-parts":[[2017,5,11]],"date-time":"2017-05-11T12:03:29Z","timestamp":1494504209000},"page":"10319-10327","source":"Crossref","is-referenced-by-count":19,"title":["Coordination Behavior of [Cp\u2032\u2032<sub>2<\/sub>Zr(\u03b7<sup>1:1<\/sup>\u2010P<sub>4<\/sub>)] towards Different Lewis Acids"],"prefix":"10.1002","volume":"23","author":[{"given":"Andreas E.","family":"Seitz","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ulf","family":"Vogel","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miriam","family":"Eberl","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria","family":"Eckhardt","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G\u00e1bor","family":"Bal\u00e1zs","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9870-9928","authenticated-orcid":false,"given":"Eugenia V.","family":"Peresypkina","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"},{"name":"Nikolaev Institute of Inorganic Chemistry Siberian Division of RAS  Acad. Lavrentiev str. 3 630090 Novosibirsk Russia"},{"name":"Novosibirsk State University  Pirogova str. 2 630090 Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Bodensteiner","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Zabel","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2182-5020","authenticated-orcid":false,"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstr. 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,6,23]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"See for example:"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1134230"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b819621d"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409800"},{"key":"e_1_2_7_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409800"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00036a008"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(95)00522-R"},{"key":"e_1_2_7_7_2","volume-title":"Activation of Small Molecules: Organometallic and Bioinorganic Perspectives","year":"2006"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature02274"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1141474"},{"key":"e_1_2_7_10_1","unstructured":"For As please see:"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(89)85154-X"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199011041"},{"key":"e_1_2_7_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19901021006"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19901230102"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19901230310"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar970317c"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404653"},{"key":"e_1_2_7_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404653"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC03543G"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00501a019"},{"key":"e_1_2_7_19_1","unstructured":"For P please see:"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003709"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_7_22_1","unstructured":"For P please see:"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2010.12.016"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc17449a"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/b718179p"},{"key":"e_1_2_7_27_1","unstructured":"\u00a0"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197904691"},{"key":"e_1_2_7_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19790910621"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198203301"},{"key":"e_1_2_7_29_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19820940503"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50225a047"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/om9806794"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305315"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201305315"},{"key":"e_1_2_7_33_1","unstructured":"\u00a0"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20011015)40:20<3910::AID-ANIE3910>3.0.CO;2-2"},{"key":"e_1_2_7_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20011015)113:20<4028::AID-ANGE4028>3.0.CO;2-O"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/b504795a"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2006.05.049"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200900884"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2009.12.022"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201330"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411451"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201411451"},{"key":"e_1_2_7_41_1","unstructured":"\u00a0"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja002007m"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20020201)8:3<700::AID-CHEM700>3.0.CO;2-C"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201208226"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201208226"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302882"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201302882"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201306146"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201306146"},{"key":"e_1_2_7_47_1","unstructured":"\u00a0"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00737a059"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00263a010"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00351a067"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198806941"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19881000531"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07389"},{"key":"e_1_2_7_53_1","unstructured":"A.\u2005E. Seitz Master\u2032s Thesis University of Regensburg 2013."},{"key":"e_1_2_7_54_1","unstructured":"\u00a0"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199109691"},{"key":"e_1_2_7_55_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911030836"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00058a012"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(92)83465-T"},{"key":"e_1_2_7_58_1","unstructured":"The synthesis was developed based on modified literature procedures:"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9822815"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(89)85406-3"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9810293"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00395a068"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/om049273j"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00163a057"},{"key":"e_1_2_7_65_1","unstructured":"For details see Supporting Information."},{"key":"e_1_2_7_66_1","unstructured":"\u00a0"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1749580"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901472"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.449486"},{"key":"e_1_2_7_70_1","unstructured":"Note that the reaction of1with [Cr(CO)5(thf)] in a 1:1 ratio leads to the isostructural complex [Cp\u2032\u20322Zr(\u03bc \u03b71:1:1-P4){Cr(CO)5}]. For details see Supporting Information."},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/om801118k"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/om030570i"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3749(200107)627:7<1593::AID-ZAAC1593>3.0.CO;2-#"},{"key":"e_1_2_7_74_1","unstructured":"Despite several attempts it was not possible to isolate4as analytically pure crystalline material. Please note that the column chromatographic work-up of such a type of zirconium complexes is often hardly practicable due to decomposition of the products."},{"key":"e_1_2_7_75_1","unstructured":"Since no tungsten satellites could be observed due to a bad signal-to-noise ratio a final assignment of PA PM PX and PX\u2032seemed not to be reasonable."},{"key":"e_1_2_7_76_1","unstructured":"Note that no fraction containing5\u2009acould be isolated by column chromatographic work-up and therefore no further analytical investigations could be performed."},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1139\/v73-451"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197505721"},{"key":"e_1_2_7_78_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19750871616"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197507051"},{"key":"e_1_2_7_79_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19750871912"},{"key":"e_1_2_7_80_1","unstructured":"The31P\u2005NMR spectrum of the reaction mixture indicates the formation of the isomer8\u2009awhose isolation was not possible despite several attempts."},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19966220606"},{"key":"e_1_2_7_82_1","unstructured":"Beside the 1:2 stoichiometry the reaction of1and AlMe3was examined in a 1:1 and a 1:5 stoichiometry resulting solely in the formation of9. Interestingly 1was observed in the case of the 1:1 stoichiometry in the31P\u2005NMR spectrum of the supernatant after crystallization of9but not in the31P\u2005NMR spectrum of the reaction mixture. No other species were detected in the31P\u2005NMR spectra of the reaction mixture and the supernatant after crystallization of9from a 1:5 stoichiometric reaction."}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201701380","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201701380","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.201701380","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201701380","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T17:23:59Z","timestamp":1760289839000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201701380"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,6,23]]},"references-count":97,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2017,8]]}},"alternative-id":["10.1002\/chem.201701380"],"URL":"https:\/\/doi.org\/10.1002\/chem.201701380","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,6,23]]}}}