{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T16:35:42Z","timestamp":1780331742297,"version":"3.54.1"},"reference-count":47,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2017,7,7]],"date-time":"2017-07-07T00:00:00Z","timestamp":1499385600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003549","name":"Orsz\u00e1gos Tudom\u00e1nyos Kutat\u00e1si Alapprogramok","doi-asserted-by":"publisher","award":["NN 113772"],"award-info":[{"award-number":["NN 113772"]}],"id":[{"id":"10.13039\/501100003549","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A series of triphospha[3]ferrocenophanes of the type Fe(C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>\u2010P<jats:italic>t<\/jats:italic>Bu)<jats:sub>2<\/jats:sub>PX with X=H, F, Cl, Br, I, NEt<jats:sub>2<\/jats:sub>, <jats:italic>t<\/jats:italic>Bu has been prepared and characterized by heteronuclear NMR spectroscopy and X\u2010ray crystallography. Despite having three stereogenic centers, the selective formation of a reduced number of diastereomers (either one or two) has been observed for these ferrocenophanes. Theoretical calculations revealed that the inversion of the central stereogenic center inverts the frontier orbital sequence leading to either an iron or a phosphorus centered HOMO depending on the respective diastereomer. CV measurements supported these results. For the all\u2010<jats:italic>tert<\/jats:italic>\u2010butyl substituted [3]ferrocenophane Fe(C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(P<jats:italic>t<\/jats:italic>Bu)<jats:sub>3<\/jats:sub> a chiral staggered conformation has been found in the solid state which differs substantially from the only other all\u2010organo substituted [3]ferrocenophane, Fe(C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(PPh)<jats:sub>3<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/chem.201701905","type":"journal-article","created":{"date-parts":[[2017,5,30]],"date-time":"2017-05-30T09:52:18Z","timestamp":1496137938000},"page":"10438-10450","source":"Crossref","is-referenced-by-count":23,"title":["Stereochemical Alignment in Triphospha[3]ferrocenophanes"],"prefix":"10.1002","volume":"23","author":[{"given":"Stefan","family":"Borucki","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie und CINSaT Universit\u00e4t Kassel  Heinrich Plett-Stra\u00dfe 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zsolt","family":"Kelemen","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und CINSaT Universit\u00e4t Kassel  Heinrich Plett-Stra\u00dfe 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Maurer","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und CINSaT Universit\u00e4t Kassel  Heinrich Plett-Stra\u00dfe 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Clemens","family":"Bruhn","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und CINSaT Universit\u00e4t Kassel  Heinrich Plett-Stra\u00dfe 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"L\u00e1szl\u00f3","family":"Nyul\u00e1szi","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Analytical Chemistry Budapest University of Technology and Economics  Szent Gell\u00e9rt t\u00e9r 4 1111 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rudolf","family":"Pietschnig","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und CINSaT Universit\u00e4t Kassel  Heinrich Plett-Stra\u00dfe 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,7,7]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604409"},{"key":"e_1_2_7_3_2","first-page":"415","volume-title":"Strained heteroatom-bridged metallocenophanes.","author":"Manners I.","year":"2004"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1066321"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr960113u"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00196C"},{"key":"e_1_2_7_7_1","unstructured":"\u00a0"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902255"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2012.04.022"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1080\/10426507.2014.984025"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT03729A"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00320a019"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(93)80335-9"},{"key":"e_1_2_7_14_1","unstructured":"\u00a0"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200600429"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010518)40:10<1865::AID-ANIE1865>3.0.CO;2-7"},{"key":"e_1_2_7_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010518)113:10<1917::AID-ANGE1917>3.0.CO;2-1"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT03107A"},{"key":"e_1_2_7_18_1","unstructured":"\u00a0"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00023a070"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400153"},{"key":"e_1_2_7_21_1","unstructured":"\u00a0"},{"key":"e_1_2_7_22_2","first-page":"331","volume-title":"Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis","author":"Hahn J.","year":"1987"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(76)80030-9"},{"key":"e_1_2_7_24_1","unstructured":"\u00a0"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01639a012"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.462570"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9600827"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-1980-29222"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19590921102"},{"key":"e_1_2_7_30_1","unstructured":"\u00a0"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201500892"},{"key":"e_1_2_7_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201500892"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja057827j"},{"key":"e_1_2_7_33_2","unstructured":"S. Weller S. Schlindwein R. Pietschnig L. Nyul\u00e1szi D. Gudat Synthesis and Reactivity of 1 1\u2032-Ferrocenyl-Diamino-Phosphane EWPC-14 Cluj-Napoca Romania 2017 O10."},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2004.11.043"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)01132-9"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19701030112"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/B604501D"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00151a020"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/dt9950001245"},{"key":"e_1_2_7_40_1","unstructured":"M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone B. Mennucci G.\u2005A. Petersson H. Nakatsuji M. Caricato X. Li H.\u2005P. Hratchian A.\u2005F. Izmaylov J. Bloino G. Zheng J.\u2005L. Sonnenberg M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai T. Vreven J. Montgomery J.\u2005A. J.\u2005E. Peralta F. Ogliaro M. Bearpark J.\u2005J. Heyd E. Brothers K.\u2005N. Kudin V.\u2005N. Staroverov T. Keith R. Kobayashi J. Normand K. Raghavachari A. Rendell J.\u2005C. Burant S.\u2005S. Iyengar J. Tomasi M. Cossi N. Rega J.\u2005M. Millam M. Klene J.\u2005E. Knox J.\u2005B. Cross V. Bakken C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski R.\u2005L. Martin K. Morokuma V.\u2005G. Zakrzewski G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg S. Dapprich A.\u2005D. Daniels O. Farkas J.\u2005B. Foresman J.\u2005V. Ortiz J. Cioslowski D.\u2005J. FoxGaussian 09 Revision B.01 Gaussian Inc. Wallington CT 2010."},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1008193805436"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_7_43_1","unstructured":"\u00a0"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889899006020"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1107\/S002188980600731X"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201701905","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201701905","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.201701905","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201701905","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T17:24:06Z","timestamp":1760289846000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201701905"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,7,7]]},"references-count":47,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2017,8]]}},"alternative-id":["10.1002\/chem.201701905"],"URL":"https:\/\/doi.org\/10.1002\/chem.201701905","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,7,7]]}}}