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The versatile product scope enables the preparation of both industrially relevant organophosphorus compounds, as well as a broad range of intriguing new compound classes. Herein we provide a concise overview of recent breakthroughs and outline the acquired fundamental insights to aid future developments.<\/jats:p>","DOI":"10.1002\/chem.201702067","type":"journal-article","created":{"date-parts":[[2017,5,11]],"date-time":"2017-05-11T22:25:57Z","timestamp":1494541557000},"page":"11738-11746","source":"Crossref","is-referenced-by-count":86,"title":["Functionalization of P<sub>4<\/sub> through Direct P\u2212C Bond Formation"],"prefix":"10.1002","volume":"23","author":[{"given":"Jaap E.","family":"Borger","sequence":"first","affiliation":[{"name":"Department of Chemistry and Pharmaceutical Sciences Vrije Universiteit Amsterdam  De Boelelaan 1083 1081 HV Amsterdam the Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas W.","family":"Ehlers","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Pharmaceutical Sciences Vrije Universiteit Amsterdam  De Boelelaan 1083 1081 HV Amsterdam the Netherlands"},{"name":"Department of Chemistry University of Johannesburg  Auckland Park Johannesburg 2006 South Africa"},{"name":"Current address: Van \u201ct Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 1098 XH Amsterdam the Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J. Chris","family":"Slootweg","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Pharmaceutical Sciences Vrije Universiteit Amsterdam  De Boelelaan 1083 1081 HV Amsterdam the Netherlands"},{"name":"Current address: Van \u201ct Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 1098 XH Amsterdam the Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9162-5783","authenticated-orcid":false,"given":"Koop","family":"Lammertsma","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Pharmaceutical Sciences Vrije Universiteit Amsterdam  De Boelelaan 1083 1081 HV Amsterdam the Netherlands"},{"name":"Department of Chemistry University of Johannesburg  Auckland Park Johannesburg 2006 South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,7,27]]},"reference":[{"key":"e_1_2_10_1_1","volume-title":"Phosphorus 2000","author":"Corbridge D. 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