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Sonochemically synthesized TMU\u201034 powder has been employed in the sensing of volatile organic compounds (VOCs). The results show that TMU\u201034 can act as a solid\u2010state, naked\u2010eye visual chemosensor for the detection of chloroform in the liquid and gas phases. TMU\u201034, as a chemo\u2010switchable MOF with rapid response, undergoes a significant color change from yellow to pink through reversible dynamic conversion of dihydrotetrazine into tetrazine upon exposure to chloroform in the presence of other VOCs. Whereas other colorimetric MOF\u2010based sensors show a wide range of color changes in the presence of different analytes, TMU\u201034 undergoes a color change only in the presence of chloroform. A mechanism for the observed color change is proposed on the basis of UV\/Vis and <jats:sup>1<\/jats:sup>H\u2005NMR spectroscopic studies. These observations reveal that TMU\u201034 represents one of the most promising candidates for the highly selective and sensitive detection of chloroform.<\/jats:p>","DOI":"10.1002\/chem.201702127","type":"journal-article","created":{"date-parts":[[2017,6,17]],"date-time":"2017-06-17T17:44:45Z","timestamp":1497721485000},"page":"12559-12564","source":"Crossref","is-referenced-by-count":84,"title":["Stimuli\u2010Responsive Metal\u2013Organic Framework (MOF) with Chemo\u2010Switchable Properties for Colorimetric Detection of CHCl<sub>3<\/sub>"],"prefix":"10.1002","volume":"23","author":[{"given":"Sayed Ali Akbar","family":"Razavi","sequence":"first","affiliation":[{"name":"Department of Chemistry Faculty of Science Tarbiat Modares University  Tehran Islamic Republic of Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1329-5947","authenticated-orcid":false,"given":"Mohammad Yaser","family":"Masoomi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Tarbiat Modares University  Tehran Islamic Republic of Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1828-7287","authenticated-orcid":false,"given":"Ali","family":"Morsali","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Tarbiat Modares University  Tehran Islamic Republic of Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,8,10]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"crossref","first-page":"658","DOI":"10.1002\/j.1551-8833.1977.tb06845.x","author":"Tardiff R.","year":"1977","journal-title":"J. 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