{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T22:35:41Z","timestamp":1788906941091,"version":"build-2803163510"},"reference-count":118,"publisher":"Wiley","issue":"40","license":[{"start":{"date-parts":[[2017,6,27]],"date-time":"2017-06-27T00:00:00Z","timestamp":1498521600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21372046, 21532001"],"award-info":[{"award-number":["21372046, 21532001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,7,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A four\u2010component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, alkenes, and hydroxylamines under mild conditions is accomplished. No catalyst or additive is needed for the vicinal difunctionalization of alkenes with the insertion of sulfur dioxide. Not only DABCO\u22c5(SO<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub> (DABCO=1,4\u2010diazabicyclo[2.2.2]octane) but also potassium metabisulfite (K<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub>) is effective in this transformation. The multicomponent reaction proceeds efficiently at room temperature with broad substrate scope, leading to the corresponding products in good yields.<\/jats:p>","DOI":"10.1002\/chem.201702190","type":"journal-article","created":{"date-parts":[[2017,6,9]],"date-time":"2017-06-09T08:39:43Z","timestamp":1496997583000},"page":"9477-9480","source":"Crossref","is-referenced-by-count":89,"title":["Vicinal Difunctionalization of Alkenes through a Multicomponent Reaction with the Insertion of Sulfur Dioxide"],"prefix":"10.1002","volume":"23","author":[{"given":"Jun","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Chemistry Fudan University  220 Handan Road Shanghai 200433 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanyuan","family":"An","sequence":"additional","affiliation":[{"name":"Department of Chemistry Fudan University  220 Handan Road Shanghai 200433 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Fudan University  220 Handan Road Shanghai 200433 P. R. China"},{"name":"State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences  345 Lingling Road Shanghai 200032 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,6,27]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"For selected reviews see:"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/B607474J"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b607819m"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic061997v"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/b813246a"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100371y"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0031-1289668"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2014.05.077"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.6b01058"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201301637"},{"key":"e_1_2_2_11_1","unstructured":"For oxysulfonylation of alkenes see:"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4OB00776J"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5OB00742A"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc45803b"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.5b01176"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301634"},{"key":"e_1_2_2_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201301634"},{"key":"e_1_2_2_17_2","first-page":"5360","volume":"18","author":"Yang D.","year":"2016","journal-title":"Green Chem."},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC00090A"},{"key":"e_1_2_2_19_1","unstructured":"For oxyalkylation of alkenes see:"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja410195j"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc51466h"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201405102"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201400548"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201412357"},{"key":"e_1_2_2_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201412357"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201403097"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b02177"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201612365"},{"key":"e_1_2_2_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201612365"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201700049"},{"key":"e_1_2_2_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201700049"},{"key":"e_1_2_2_29_2","first-page":"2017","author":"Zhao J.","journal-title":"Adv. Synth. Catal."},{"key":"e_1_2_2_30_1","unstructured":"For oxyamination of alkenes see:"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b02703"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b01368"},{"key":"e_1_2_2_33_1","unstructured":"For dioxygenation of alkenes see:"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b01741"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6QO00318D"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.6b01988"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6OB00210B"},{"key":"e_1_2_2_38_1","unstructured":"For some other difunctionalization of alkenes see:"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja307638u"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b02347"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02718"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b00337"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b03295"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2015.02.043"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5131676"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201601211"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC05093J"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC01531C"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702349"},{"key":"e_1_2_2_49_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201702349"},{"key":"e_1_2_2_50_1","unstructured":"For selected examples see:"},{"key":"e_1_2_2_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607292"},{"key":"e_1_2_2_51_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201607292"},{"key":"e_1_2_2_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201309851"},{"key":"e_1_2_2_52_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201309851"},{"key":"e_1_2_2_53_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6QO00060F"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5QO00399G"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6QO00070C"},{"key":"e_1_2_2_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6QO00163G"},{"key":"e_1_2_2_57_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7QO00026J"},{"key":"e_1_2_2_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7QO00075H"},{"key":"e_1_2_2_59_1","unstructured":"\u00a0"},{"key":"e_1_2_2_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1081124"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ob07034k"},{"key":"e_1_2_2_62_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4OB02139H"},{"key":"e_1_2_2_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ob40997j"},{"key":"e_1_2_2_64_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0034-1379042"},{"key":"e_1_2_2_65_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-981-10-4202-7"},{"key":"e_1_2_2_66_1","unstructured":"\u00a0"},{"key":"e_1_2_2_67_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6QO00099A"},{"key":"e_1_2_2_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201601617"},{"key":"e_1_2_2_69_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201605336"},{"key":"e_1_2_2_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201402212"},{"key":"e_1_2_2_71_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC03481C"},{"key":"e_1_2_2_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol5018849"},{"key":"e_1_2_2_73_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409283"},{"key":"e_1_2_2_73_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409283"},{"key":"e_1_2_2_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00015"},{"key":"e_1_2_2_75_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol403122a"},{"key":"e_1_2_2_76_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol4031233"},{"key":"e_1_2_2_77_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305369"},{"key":"e_1_2_2_77_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201305369"},{"key":"e_1_2_2_78_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404527"},{"key":"e_1_2_2_78_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404527"},{"key":"e_1_2_2_79_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol403072r"},{"key":"e_1_2_2_80_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400037"},{"key":"e_1_2_2_80_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400037"},{"key":"e_1_2_2_81_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201505918"},{"key":"e_1_2_2_81_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201505918"},{"key":"e_1_2_2_82_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201508370"},{"key":"e_1_2_2_82_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201508370"},{"key":"e_1_2_2_83_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b03545"},{"key":"e_1_2_2_84_1","unstructured":"\u00a0"},{"key":"e_1_2_2_85_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC09830K"},{"key":"e_1_2_2_86_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6QO00530F"},{"key":"e_1_2_2_87_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC03924C"},{"key":"e_1_2_2_88_2","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201600518"},{"key":"e_1_2_2_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b00051"},{"key":"e_1_2_2_90_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201601341"},{"key":"e_1_2_2_91_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc33725h"},{"key":"e_1_2_2_92_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201400334"},{"key":"e_1_2_2_93_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC05401F"},{"key":"e_1_2_2_94_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC07938H"},{"key":"e_1_2_2_95_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC03032J"},{"key":"e_1_2_2_96_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5OB01765C"},{"key":"e_1_2_2_97_1","doi-asserted-by":"crossref","unstructured":"T. Liu D. Zheng Z. Li J. Wu Adv. Synth. Catal.2017 https:\/\/doi.org\/10.1002\/adsc.201700501.","DOI":"10.1002\/adsc.201700501"},{"key":"e_1_2_2_98_1","unstructured":"CCDC\u20051542643(4\u2009s) contain the supplementary crystallographic data for this paper. These data are provided free of charge byThe Cambridge Crystallographic Data Centre."},{"key":"e_1_2_2_99_1","unstructured":"For examples of persistent radical effect see:"},{"key":"e_1_2_2_100_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr990124y"},{"key":"e_1_2_2_101_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20010316)7:6<1159::AID-CHEM1159>3.0.CO;2-I"},{"key":"e_1_2_2_102_2","doi-asserted-by":"publisher","DOI":"10.1039\/b307652k"},{"key":"e_1_2_2_103_2","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.20033"},{"key":"e_1_2_2_104_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc34957d"},{"key":"e_1_2_2_105_1","doi-asserted-by":"crossref","unstructured":"Y. Wang B. Du W. Sha J. Han Y. Pan Org. Chem. Front.2017 https:\/\/doi.org\/10.1039\/c7qo00168a.","DOI":"10.1039\/C7QO00168A"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201702190","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201702190","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.201702190","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201702190","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T10:46:30Z","timestamp":1760265990000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201702190"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,6,27]]},"references-count":118,"journal-issue":{"issue":"40","published-print":{"date-parts":[[2017,7,18]]}},"alternative-id":["10.1002\/chem.201702190"],"URL":"https:\/\/doi.org\/10.1002\/chem.201702190","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,6,27]]}}}