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Using an equimolar mixture of Fe<jats:sup>2+<\/jats:sup>, Co<jats:sup>2+<\/jats:sup>, and Fe<jats:sup>3+<\/jats:sup> during co\u2010precipitation, a mixture of LDH, (Fe<jats:sup>II<\/jats:sup>Co<jats:sup>II<\/jats:sup>)<jats:sub>2\/3<\/jats:sub>Fe<jats:sup>III<\/jats:sup><jats:sub>1\/3<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>(CO<jats:sub>3<\/jats:sub>)<jats:sub>1\/6<\/jats:sub><jats:bold>\u22c5<\/jats:bold><jats:italic>m<\/jats:italic>\u2009H<jats:sub>2<\/jats:sub>O, and the target spinel CoFe<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub> can be obtained in the precursor. During calcination, the remaining Fe<jats:sup>II<\/jats:sup> fraction of the LDH is oxidized to Fe<jats:sup>III<\/jats:sup> leading to an overall Co<jats:sup>2+<\/jats:sup>:Fe<jats:sup>3+<\/jats:sup> ratio of 1:2 as required for spinel crystallization. This pre\u2010adjustment of the spinel composition in the LDH precursor suggests a topotactic crystallization of cobalt ferrite and yields phase pure spinel in unusual anisotropic platelet morphology. The preferred topotactic relationship in most particles is [111]<jats:sub>Spinel<\/jats:sub>\u2225[001]<jats:sub>LDH<\/jats:sub>. Due to the anion decomposition, holes are formed throughout the quasi monocrystalline platelets. This synthesis approach can be used for different ferrites and the unique microstructure leads to unusual chemical properties as shown by the application of the ex\u2010LDH cobalt ferrite as catalyst in the selective oxidation of 2\u2010propanol. Compared to commercial cobalt ferrite, which mainly catalyzes the oxidative dehydrogenation to acetone, the main reaction over the novel ex\u2010LDH cobalt is dehydration to propene. Moreover, the oxygen evolution reaction (OER) activity of the ex\u2010LDH catalyst was markedly higher compared to the commercial material.<\/jats:p>","DOI":"10.1002\/chem.201702248","type":"journal-article","created":{"date-parts":[[2017,6,28]],"date-time":"2017-06-28T10:06:46Z","timestamp":1498644406000},"page":"12443-12449","source":"Crossref","is-referenced-by-count":40,"title":["Topotactic Synthesis of Porous Cobalt Ferrite Platelets from a Layered Double Hydroxide Precursor and Their Application in Oxidation Catalysis"],"prefix":"10.1002","volume":"23","author":[{"given":"Klaus Friedel","family":"Ortega","sequence":"first","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (CENIDE) University of Duisburg-Essen  Universit\u00e4tsstr. 7 45114 Essen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sven","family":"Anke","sequence":"additional","affiliation":[{"name":"Laboratory of Industrial Chemistry Ruhr-University 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