{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T00:29:23Z","timestamp":1760315363859,"version":"build-2065373602"},"reference-count":48,"publisher":"Wiley","issue":"55","license":[{"start":{"date-parts":[[2017,9,4]],"date-time":"2017-09-04T00:00:00Z","timestamp":1504483200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004663","name":"Ministry of Science and Technology, Taiwan","doi-asserted-by":"publisher","award":["106-2113-M-007-023-MY2"],"award-info":[{"award-number":["106-2113-M-007-023-MY2"]}],"id":[{"id":"10.13039\/501100004663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,10,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In this study, \u03b1\u2010TiP layered structure incorporating a heterometal center for organic ligand binding to enhance structural complexity and functionality were prepared. The protons of the \u03b1\u2010TiP layer were replaced with zinc ions coordinated by 4\u2010pyridinecarboxylic acid (PCA) and water to form a layer structure, TiZn(PO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)(PCA) (<jats:bold>1<\/jats:bold>). The tetrahedral zinc center with coordinated water in <jats:bold>1<\/jats:bold> is unprecedented in zincophosphate or zinc\u2010MOF systems and is usually only found in metalloenzyme systems. The neutral zincotitanophosphate layers, tightly stacked through hydrogen bonds, showed velcro\u2010like behavior on intercalating 4,4\u2032\u2010trimethylenedipyridine (TMDP) reversibly. It rendered a remarkable luminescence property to <jats:bold>1<\/jats:bold>, emitting blue\u2010to\u2010white light under UV excitation. Surprisingly, the replacement of TMDP for PCA in the hydrothermal synthesis still resulted in <jats:bold>1<\/jats:bold>, plus another structure, Ti<jats:sub>4<\/jats:sub>Zn<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>TPB)(PO<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>(HPO<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>PO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub> (<jats:bold>2<\/jats:bold>) (TPB=1,2,4,5\u2010tetra(4\u2010pyridyl)benzene). Clearly, in situ C\u2212C cracking and C\u2212C coupling of TMDP simultaneously occurred to generate PCA and TPB and thereafter the oxidant, Zn(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>, was quantitatively determined to isolate crystal <jats:bold>1<\/jats:bold> from <jats:bold>2<\/jats:bold>. The structure of <jats:bold>2<\/jats:bold> also featured \u03b1\u2010TiP layers with pedant Zn tetrahedra but formed a three\u2010dimensional neutral framework through TPB. For the first time, \u03b1\u2010TiP\u2010derived structures and their properties have been elucidated, which help in understanding intriguing in situ ligand formation and intercalation\u2010induced luminescence, to exploit potential photocatalysis in polymerization.<\/jats:p>","DOI":"10.1002\/chem.201702320","type":"journal-article","created":{"date-parts":[[2017,8,10]],"date-time":"2017-08-10T12:26:37Z","timestamp":1502367997000},"page":"13583-13586","source":"Crossref","is-referenced-by-count":4,"title":["Transition Metal Titanophosphates with Intercalated Molecular Photoluminescence and Catalytic Properties"],"prefix":"10.1002","volume":"23","author":[{"given":"Ling\u2010I","family":"Hung","sequence":"first","affiliation":[{"name":"Department of Chemistry National Tsing Hua University  101, Section 2, Kuang-Fu Road Hsinchu 30013 Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pei\u2010Lin","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Tsing Hua University  101, Section 2, Kuang-Fu Road Hsinchu 30013 Taiwan"},{"name":"Instrumentation Center National Tsing Hua University  Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jia\u2010Hao","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Tsing Hua University  101, Section 2, Kuang-Fu Road Hsinchu 30013 Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chi\u2010How","family":"Peng","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Tsing Hua University  101, Section 2, Kuang-Fu Road Hsinchu 30013 Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sue\u2010Lein","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Tsing Hua University  101, Section 2, Kuang-Fu Road Hsinchu 30013 Taiwan"},{"name":"Department of Chemistry Chung Yuan Christian University  Chungli 32023 Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,9,4]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2016.04.123"},{"key":"e_1_2_2_3_2","first-page":"312","volume":"68","author":"Thakkar R.","year":"2009","journal-title":"J. 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Crystal data for2 Ti4Zn2(H2TPB)(PO4)4(HPO4)4(H2PO4)2 Mr=834.28 triclinic space groupP a=8.2585(5) b=10.3669 (1) c=15.314(1)\u2005\u00c5 \u03b1=99.515(3) \u03b2=98.541(3) \u03b3=90.037(3)\u00b0 V=1278.3(1)\u2005\u00c53Z=1 R1=0.0539 andwR2=0.1521. The crystal of2contained two twin components and the refinements showed they were about 50\u2009% for each."},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2003.10.033"},{"key":"e_1_2_2_32_1","unstructured":"\u00a0"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1093\/jn\/130.5.1437S"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi00476a001"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi4016617"},{"key":"e_1_2_2_36_1","unstructured":"Compound1(250\u2005mg) was stirred with 12.5\u2005mmol TMDP in 25\u2005mL water at 70\u2009\u00b0C for 1\u2005day and the product was collected by centrifugation. 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