{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T15:16:33Z","timestamp":1787238993869,"version":"build-2736575974"},"reference-count":45,"publisher":"Wiley","issue":"52","license":[{"start":{"date-parts":[[2017,7,31]],"date-time":"2017-07-31T00:00:00Z","timestamp":1501459200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["11502246"],"award-info":[{"award-number":["11502246"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["11402237"],"award-info":[{"award-number":["11402237"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,9,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    <jats:italic>gem<\/jats:italic>\n                    \u2010Dinitromethylated and fluorodinitromethylated 5,5\u2032\u2010dinitro\u20103,3\u2032\u2010bis\u20101,2,4\u2010triazole (DNBT) (\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    ) along with seven ionic derivatives\n                    <jats:bold>4<\/jats:bold>\n                    \u2013\n                    <jats:bold>9<\/jats:bold>\n                    , were synthesized and characterized by NMR and IR spectroscopies, elemental analysis, single\u2010crystal X\u2010ray diffraction (XRD), and differential scanning calorimetry (DSC). XRD revealed that compounds\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    crystallized in the monoclinic\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    space group and compound\n                    <jats:bold>5<\/jats:bold>\n                    crystallized in the monoclinic\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    space group. The physicochemical properties of the as\u2010synthesized compounds\n                    <jats:bold>2<\/jats:bold>\n                    \u2013\n                    <jats:bold>9<\/jats:bold>\n                    were investigated and the results indicated that compounds\n                    <jats:bold>3<\/jats:bold>\n                    ,\n                    <jats:bold>6<\/jats:bold>\n                    , and\n                    <jats:bold>7<\/jats:bold>\n                    exhibited a good balance between high energy and low sensitivity, demonstrating their potential as new high\u2010energy\u2010density materials (HEDMs). The proposed synthetic strategy for introducing\n                    <jats:italic>gem<\/jats:italic>\n                    \u2010dinitromethyl and fluorodinitromethyl groups into the DNBT framework to prepare materials with high energy and low sensitivity suitable for HEDMs looks promising.\n                  <\/jats:p>","DOI":"10.1002\/chem.201702451","type":"journal-article","created":{"date-parts":[[2017,6,19]],"date-time":"2017-06-19T05:36:42Z","timestamp":1497850602000},"page":"12787-12794","source":"Crossref","is-referenced-by-count":41,"title":["Synthesis of\n                    <i>gem<\/i>\n                    \u2010Dinitromethylated and Fluorodinitromethylated Derivatives of 5,5\u2032\u2010Dinitro\u2010bis\u20101,2,4\u2010triazole as Promising High\u2010Energy\u2010Density Materials"],"prefix":"10.1002","volume":"23","author":[{"given":"Shi","family":"Huang","sequence":"first","affiliation":[{"name":"Research Center of Energetic Materials Genome Science Institute of Chemical Materials China Academy of Engineering Physics (CAEP)  Mianyang 621900 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junjun","family":"Tian","sequence":"additional","affiliation":[{"name":"Research Center of Energetic Materials Genome Science Institute of Chemical Materials China Academy of Engineering Physics (CAEP)  Mianyang 621900 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiujuan","family":"Qi","sequence":"additional","affiliation":[{"name":"School of Material Science and Engineering Southwest University of Science and Technology  Mianyang 621900 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kangcai","family":"Wang","sequence":"additional","affiliation":[{"name":"Research Center of Energetic Materials Genome Science Institute of Chemical Materials China Academy of Engineering Physics (CAEP)  Mianyang 621900 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4162-7155","authenticated-orcid":false,"given":"Qinghua","family":"Zhang","sequence":"additional","affiliation":[{"name":"Research Center of Energetic Materials Genome Science Institute of Chemical Materials China Academy of Engineering Physics (CAEP)  Mianyang 621900 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,7,31]]},"reference":[{"key":"e_1_2_7_1_1","volume-title":"Organic Chemistry of Explosives","author":"Agrawal J. P.","year":"2007"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0360-1285(97)00015-4"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/427580a"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500364t"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1515\/9783110227840"},{"key":"e_1_2_7_6_1","volume-title":"Explosives for North American Engineers, vol. 5","author":"Gregory C. E.","year":"1984"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2010.04.120"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200039c"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000117)39:2<401::AID-ANIE401>3.0.CO;2-P"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(20000117)112:2<422::AID-ANGE422>3.0.CO;2-2"},{"key":"e_1_2_7_10_1","first-page":"526","volume":"20","author":"Yang S.","year":"2008","journal-title":"Prog. Chem."},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm703657k"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/prep.200400050"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT00888C"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201605611"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201605611"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA01501H"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA06139J"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606378"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606378"},{"key":"e_1_2_7_18_1","first-page":"1","volume":"24","author":"Tian J. -J.","year":"2016","journal-title":"Chin. J. Energ. Mater."},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-540-72202-1"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201202483"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507456"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201507456"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506744"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201506744"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja404164j"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja1055033"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic400919n"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA00175G"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja5126275"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mencom.2010.11.010"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2009.02.032"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11172-009-0285-y"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.20330"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2004.04.003"},{"key":"e_1_2_7_33_1","unstructured":"Gaussian\u200509 Revision D.01 M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone B. Mennucci G.\u2005A. Petersson H. Nakatsuji M. Caricato X. Li H.\u2005P. Hratchian A.\u2005F. Izmaylov J. Bloino G. Zheng J.\u2005L. Sonnenberg M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai T. Vreven J.\u2005A. Montgomery Jr. J.\u2005E. Peralta F. Ogliaro M. Bearpark J.\u2005J. Heyd E. Brothers K.\u2005N. Kudin V.\u2005N. Staroverov R. Kobayashi J. Normand K. Raghavachari A. Rendell J.\u2005C. Burant S.\u2005S. Iyengar J. Tomasi M. Cossi N. Rega J.\u2005M. Millam M. Klene J.\u2005E. Knox J.\u2005B. Cross V. Bakken C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski R.\u2005L. Martin K. Morokuma V.\u2005G. Zakrzewski G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg S. Dapprich A.\u2005D. Daniels \u00d6. Farkas J.\u2005B. Foresman J.\u2005V. Ortiz J. Cioslowski D.\u2005J. Fox Gaussian Inc. Wallingford CT 2009."},{"key":"e_1_2_7_34_1","volume-title":"Density Functional Theory of Atoms and Molecules","author":"Parr R. G.","year":"1989"},{"key":"e_1_2_7_35_1","unstructured":"\u00a0"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1080\/14786448408627563"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00123a001"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic011216k"},{"key":"e_1_2_7_39_1","unstructured":"M. Su\u0107eska EXPLO5 version 6.02 2013."},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.5028\/jatm.2009.0102211216"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201702451","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201702451","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T20:03:51Z","timestamp":1760299431000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201702451"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,7,31]]},"references-count":45,"journal-issue":{"issue":"52","published-print":{"date-parts":[[2017,9,18]]}},"alternative-id":["10.1002\/chem.201702451"],"URL":"https:\/\/doi.org\/10.1002\/chem.201702451","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,7,31]]}}}