{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,24]],"date-time":"2026-04-24T07:28:25Z","timestamp":1777015705550,"version":"3.51.4"},"reference-count":32,"publisher":"Wiley","issue":"52","license":[{"start":{"date-parts":[[2017,8,18]],"date-time":"2017-08-18T00:00:00Z","timestamp":1503014400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["SCHU 1170\/9-1"],"award-info":[{"award-number":["SCHU 1170\/9-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,9,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The chemistry of arsenic cyanides has been investigated and is found to be completely different to the chemistry of the heavier analogs antimony and bismuth as well as phosphorus. The reaction of As(CN)<jats:sub>3<\/jats:sub> with cyanide salts resulted in the formation of an unknown cyanido arsazolide heterocycle, which represents a structure isomer of the desired [As(CN)<jats:sub>4<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>. The structure, bonding, and formation of this unusual heterocycle is discussed featuring an arsenic mediated C\u2212C coupling of cyanides. [AsC<jats:sub>4<\/jats:sub>N<jats:sub>4<\/jats:sub>]<jats:sup>\u2212<\/jats:sup> salts with different counterions such as [PPh<jats:sub>4<\/jats:sub>]<jats:sup>+<\/jats:sup>, [PPN]<jats:sup>+<\/jats:sup>=[Ph<jats:sub>3<\/jats:sub>P\u2010<jats:italic>N<\/jats:italic>\u2010PPh<jats:sub>3<\/jats:sub>]<jats:sup>+<\/jats:sup>, Ag<jats:sup>+<\/jats:sup>, and [BMIm]<jats:sup>+<\/jats:sup> are reported with [BMIm][AsC<jats:sub>4<\/jats:sub>N<jats:sub>4<\/jats:sub>] being a low\u2010temperature ionic liquid (<jats:italic>T<\/jats:italic><jats:sub>m<\/jats:sub>=\u221262\u2009\u00b0C).<\/jats:p>","DOI":"10.1002\/chem.201703317","type":"journal-article","created":{"date-parts":[[2017,8,18]],"date-time":"2017-08-18T02:33:02Z","timestamp":1503023582000},"page":"12735-12738","source":"Crossref","is-referenced-by-count":12,"title":["Arsenic\u2010Mediated C\u2212C Coupling of Cyanides Leading to Cyanido Arsazolide [AsC<sub>4<\/sub>N<sub>4<\/sub>]<sup>\u2212<\/sup>"],"prefix":"10.1002","volume":"23","author":[{"given":"S\u00f6ren","family":"Arlt","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3\u2009a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J\u00f6rg","family":"Harloff","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3\u2009a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9060-7065","authenticated-orcid":false,"given":"Axel","family":"Schulz","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3\u2009a 18059 Rostock Germany"},{"name":"Leibniz-Institut f\u00fcr Katalyse e.V. an der Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 29\u2009a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alrik","family":"Stoffers","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3\u2009a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"Villinger","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3\u2009a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,8,18]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.18631280218"},{"key":"e_1_2_2_2_1","first-page":"1186","volume":"114","author":"Guenez E.","year":"1892","journal-title":"C. R. Hebd. Seances Acad. Sci."},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01549a010"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50095a007"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X63000268"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X64002948"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201603849"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201602436"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19790911208"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19770891020"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19851180325"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19790910524"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02174"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901472"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C39860001633"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00047a024"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1139\/v96-248"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/hc.520030212"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302725"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201302725"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704367"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704367"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC03515E"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201605143"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201605143"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200010)2000:10<2173::AID-EJIC2173>3.0.CO;2-Y"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/om049767g"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19861190131"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201200376"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg101060s"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201200790"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1387-3806(01)00575-9"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201703317","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201703317","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T20:05:11Z","timestamp":1760299511000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201703317"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,8,18]]},"references-count":32,"journal-issue":{"issue":"52","published-print":{"date-parts":[[2017,9,18]]}},"alternative-id":["10.1002\/chem.201703317"],"URL":"https:\/\/doi.org\/10.1002\/chem.201703317","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,8,18]]}}}