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Their solid\u2010state structures and geometric parameters were determined and compared to those of other classes of thiocarbonylthio compounds. These new organotin derivatives are efficient reversible chain\u2010transfer agents for reversible addition\u2013fragmentation chain transfer (RAFT) polymerization of styrene (St) and <jats:italic>n<\/jats:italic>\u2010butyl acrylate (BA), with controlled number\u2010average molecular weights and narrow dispersities (<jats:italic>\u00d0<\/jats:italic>&lt;1.3). In some cases, loss of control of the polymerization was evidenced and supported by the observation of side products by <jats:sup>119<\/jats:sup>Sn NMR spectroscopy. This phenomenon was attributed to the thermal instability of the Sn\u2010RAFT terminal group.<\/jats:p>","DOI":"10.1002\/chem.201703412","type":"journal-article","created":{"date-parts":[[2017,8,29]],"date-time":"2017-08-29T22:22:39Z","timestamp":1504045359000},"page":"16066-16077","source":"Crossref","is-referenced-by-count":7,"title":["Alkyl Triarylstannanecarbodithioates: Synthesis, Crystal Structures, and Efficiency in RAFT Polymerization"],"prefix":"10.1002","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8812-8599","authenticated-orcid":false,"given":"Ihor","family":"Kulai","sequence":"first","affiliation":[{"name":"Laboratoire des IMRCP Universit\u00e9 Paul Sabatier, CNRS UMR 5623  118 route de Narbonne 31062 Toulouse Cedex 9 France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nathalie","family":"Saffon\u2010Merceron","sequence":"additional","affiliation":[{"name":"Institut de Chimie de Toulouse, CNRS FR 2599 Universit\u00e9 Paul Sabatier  118 route de Narbonne 31062 Toulouse Cedex 9 France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zoia","family":"Voitenko","sequence":"additional","affiliation":[{"name":"Department of Chemistry Taras Shevchenko National University of Kyiv  12, Lva Tolstoho street 01033 Kyiv Ukraine"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"St\u00e9phane","family":"Mazi\u00e8res","sequence":"additional","affiliation":[{"name":"Laboratoire des IMRCP Universit\u00e9 Paul Sabatier, CNRS UMR 5623  118 route de Narbonne 31062 Toulouse Cedex 9 France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9718-2239","authenticated-orcid":false,"given":"Mathias","family":"Destarac","sequence":"additional","affiliation":[{"name":"Laboratoire des IMRCP Universit\u00e9 Paul Sabatier, CNRS UMR 5623  118 route de Narbonne 31062 Toulouse Cedex 9 France"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,11,8]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1071\/CH12295"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/masy.19961110104"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma9804951"},{"key":"e_1_2_7_4_1","unstructured":"T. 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