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The compounds were characterized by NMR spectroscopy (<jats:sup>1<\/jats:sup>H, <jats:sup>13<\/jats:sup>C, <jats:sup>119<\/jats:sup>Sn, <jats:sup>195<\/jats:sup>Pt), <jats:sup>119<\/jats:sup>Sn M\u00f6ssbauer spectroscopy (<jats:bold>1<\/jats:bold>\u2013<jats:bold>3<\/jats:bold>, <jats:bold>6<\/jats:bold>), electrospray ionization mass spectrometry, elemental analyses, and single\u2010crystal X\u2010ray diffraction analyses (<jats:bold>2\u22c5<\/jats:bold>CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, <jats:bold>3\u22c5<\/jats:bold>2\u2009C<jats:sub>4<\/jats:sub>H<jats:sub>8<\/jats:sub>O, <jats:bold>5<\/jats:bold>, <jats:bold>6\u22c5<\/jats:bold>3CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>). The tin(II) aminoalkoxide [MeN(CH<jats:sub>2<\/jats:sub>CMe<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>Sn]<jats:sub>2<\/jats:sub> (<jats:bold>1<\/jats:bold>) behaves like a neutral ligand, inserts into a Pt\u2212Cl bond, or is involved in rearrangement reactions with the different behavior occurring even within one compound (<jats:bold>3<\/jats:bold>, <jats:bold>6<\/jats:bold>). DFT calculations show that the tin\u2013platinum compounds behave like electronic chameleons.<\/jats:p>","DOI":"10.1002\/chem.201703520","type":"journal-article","created":{"date-parts":[[2018,1,31]],"date-time":"2018-01-31T10:47:36Z","timestamp":1517395656000},"page":"5551-5561","source":"Crossref","is-referenced-by-count":8,"title":["Rational Syntheses and Serendipity: Complexes [LSnPtCl<sub>2<\/sub>(SMe<sub>2<\/sub>)]<sub>2<\/sub>, [{LSnPtCl(SMe<sub>2<\/sub>)}<sub>2<\/sub>SnCl<sub>2<\/sub>], [(LSn)<sub>3<\/sub>(PtCl<sub>2<\/sub>)(PtClSnCl){LSn(Cl)OH}], and [O(SnCl)<sub>2<\/sub>(SnL)<sub>2<\/sub>] with L=MeN(CH<sub>2<\/sub>CMe<sub>2<\/sub>O)<sub>2<\/sub>"],"prefix":"10.1002","volume":"24","author":[{"given":"Thomas","family":"Z\u00f6ller","sequence":"first","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Lehrstuhl f\u00fcr Anorganische Chemie\u2005II Technische Universit\u00e4t Dortmund  44221 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christina","family":"Dietz","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Lehrstuhl f\u00fcr Anorganische Chemie\u2005II Technische Universit\u00e4t Dortmund  44221 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Florian","family":"Winter","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie Universit\u00e4t M\u00fcnster  Corrensstrasse\u200530 48149 M\u00fcnster Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rainer","family":"P\u00f6ttgen","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie Universit\u00e4t M\u00fcnster  Corrensstrasse\u200530 48149 M\u00fcnster Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Serge I.","family":"Gorelsky","sequence":"additional","affiliation":[{"name":"Centre for Catalysis Research and Innovation Department of Chemistry University of Ottawa  Ottawa ON K1N 6N5 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"Hoffmann","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Rheinisch-Westf\u00e4lische Technische Hochschule Aachen  52074 Aachen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sonja","family":"Herres\u2010Pawlis","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Rheinisch-Westf\u00e4lische Technische Hochschule Aachen  52074 Aachen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9930-858X","authenticated-orcid":false,"given":"Klaus","family":"Jurkschat","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Lehrstuhl f\u00fcr Anorganische Chemie\u2005II Technische Universit\u00e4t Dortmund  44221 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,3,5]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01161514"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)99731-6"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200800434"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600536810019343"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201200145"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201200182"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)81517-0"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2004.08.017"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2004.03.041"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1080\/00958970600763631"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00133a062"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)01001-4"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.3184\/030823403103173110"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/DT9850000051"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C39850000548"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(90)85012-H"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt30988b"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201203511"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201100417"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201200064"},{"key":"e_1_2_7_22_1","unstructured":"M. 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